Syndiotactically enriched 1,2-selective polymerization of 1,3-butadiene initiated by iron catalysts based on a new class of donors
文献类型：期刊论文
| 作者 | Gong DR ; Dong WM ; Hu YM ; Bi JF ; Zhang XQ ; Jiang LS |
| 刊名 | polymer
 |
| 出版日期 | 2009 |
| 卷号 | 50期号:25页码:5980-5986 |
| 关键词 | SINGLE TRANSITION-STATE ISOPRENE POLYMERIZATION BUTADIENE POLYMERIZATION STEREOSPECIFIC POLYMERIZATION SELECTIVE POLYMERIZATION LIVING POLYMERIZATION DIENE POLYMERIZATION CONJUGATED DIENES AQUEOUS-SOLUTION COMPLEXES |
| ISSN号 | 0032-3861 |
| 通讯作者 | zhang xq |
| 中文摘要 | a series of phosphoryl (p=o) contained compounds: triethylphosphate (a), diethyl phenyl phosphate (b), ethyldiphenylphosphate (c) triarylphosphates (d and h-m), triphenylphosphine oxide (e), phenyl diphenylphosphinate (f) and diphenyl phenylphosphonate (g) have been prepared. iron catalysts, which are generated in situ by mixing the compounds with fe(2-eha)(3) and (albu3)-bu-i in hexane, are tested for butadiene polymerization at 50 degrees c. phosphates donated catalysts have been, unprecedently, found to conduct extremely high syndiotactically (pentad, rrrr=46.1-94.5%) enriched 1,2-selective (1,2-structure content=56.2-94.3%) polymerization of butadiene. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272284100014 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/11291]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gong DR,Dong WM,Hu YM,et al. Syndiotactically enriched 1,2-selective polymerization of 1,3-butadiene initiated by iron catalysts based on a new class of donors[J]. polymer,2009,50(25):5980-5986. |
| APA | Gong DR,Dong WM,Hu YM,Bi JF,Zhang XQ,&Jiang LS.(2009).Syndiotactically enriched 1,2-selective polymerization of 1,3-butadiene initiated by iron catalysts based on a new class of donors.polymer,50(25),5980-5986. |
| MLA | Gong DR,et al."Syndiotactically enriched 1,2-selective polymerization of 1,3-butadiene initiated by iron catalysts based on a new class of donors".polymer 50.25(2009):5980-5986. |
入库方式： OAI收割
来源：长春应用化学研究所
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