Living polymerization of 1,3-butadiene by a Ziegler-Natta type catalyst composed of iron(III) 2-ethylhexanoate, triisobutylaluminum and diethyl phosphite
文献类型：期刊论文
| 作者 | Gong DR ; Dong WM ; Hu JC ; Zhang XQ ; Jiang LS |
| 刊名 | polymer
 |
| 出版日期 | 2009 |
| 卷号 | 50期号:13页码:2826-2829 |
| 关键词 | FREE-RADICAL POLYMERIZATION BLOCK-COPOLYMER SYNTHESIS ISOPRENE POLYMERIZATION METHYL-METHACRYLATE METAL-COMPLEXES IRON COMPLEXES BUTADIENE STYRENE SYSTEM CHAIN |
| ISSN号 | 0032-3861 |
| 通讯作者 | zhang xq |
| 中文摘要 | living characteristics of facilely prepared ziegler-natta type catalyst system consisting of iron(iii) 2-ethylhexanoate, triisobutylaluminum and diethyl phosphite have been found in the polymerization of 1,3-butadiene in hexane at 40 degrees c. the characteristics have been well demonstrated by: a first-order kinetics with respect to monomer conversion, a narrow molecular weight distribution (m-w/m-n = 1.48-1.52) of polybutadiene in the entire range of polymerization conversion and a good linearity between m-n and the yield of polymer. feasible post-polymerization of 1,3-butadiene and block co-polymerization of 1,3-butadiene and isoprene further support the living natures of the catalyst bestowed with. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000267415600011 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://202.98.16.49/handle/322003/11333]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gong DR,Dong WM,Hu JC,et al. Living polymerization of 1,3-butadiene by a Ziegler-Natta type catalyst composed of iron(III) 2-ethylhexanoate, triisobutylaluminum and diethyl phosphite[J]. polymer,2009,50(13):2826-2829. |
| APA | Gong DR,Dong WM,Hu JC,Zhang XQ,&Jiang LS.(2009).Living polymerization of 1,3-butadiene by a Ziegler-Natta type catalyst composed of iron(III) 2-ethylhexanoate, triisobutylaluminum and diethyl phosphite.polymer,50(13),2826-2829. |
| MLA | Gong DR,et al."Living polymerization of 1,3-butadiene by a Ziegler-Natta type catalyst composed of iron(III) 2-ethylhexanoate, triisobutylaluminum and diethyl phosphite".polymer 50.13(2009):2826-2829. |
入库方式： OAI收割
来源：长春应用化学研究所
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