Synthesis, photophysical properties, and theoretical studies on pyrrole-containing bromo Re(I) complex
文献类型：期刊论文
| 作者 | Si ZJ ; Li XN ; Li XY ; Zhang HJ |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 694期号:23页码:3742-3748 |
| 关键词 | DENSITY-FUNCTIONAL THEORY RHENIUM(I) COMPLEXES EMITTING MATERIALS RU(II) COMPLEXES METAL-COMPLEXES ELECTROLUMINESCENCE DEVICES FILMS DERIVATIVES TRANSITION |
| ISSN号 | 0022-328x |
| 通讯作者 | zhang hj |
| 中文摘要 | two bromo rhenium(i) carbonyl complexes with the formula of [re(co)(3)(l)br], where l = 1,10-phenanthroline (phen-re) and 5-(1h-pyrrol-1-yl)-1,10-phenanthroline (pyph-re), were successfully synthesized with the aim to analyze the effect of the pyrrole (py) moiety on the photophysical properties of pyph-re. it was found that the triplet metal-to-ligand charge-transfer d pi (re) --> pi*(n-n) emission of phen-re and pyph-re centered at ca. 527 nm with the luminescence quantum yield (lqy) of 0.015 and ca. 578 nm with the lqy of 0.011, respectively. at the same time, the geometrical structures of the ground state and the absorption spectral properties of phen-re and pyph-re were also calculated with the 6-31g* basis set employed on c, h, n, o, and br atoms, and lanl2dz adopted on re atom. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000270369400009 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://202.98.16.49/handle/322003/11347]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Si ZJ,Li XN,Li XY,et al. Synthesis, photophysical properties, and theoretical studies on pyrrole-containing bromo Re(I) complex[J]. journal of organometallic chemistry,2009,694(23):3742-3748. |
| APA | Si ZJ,Li XN,Li XY,&Zhang HJ.(2009).Synthesis, photophysical properties, and theoretical studies on pyrrole-containing bromo Re(I) complex.journal of organometallic chemistry,694(23),3742-3748. |
| MLA | Si ZJ,et al."Synthesis, photophysical properties, and theoretical studies on pyrrole-containing bromo Re(I) complex".journal of organometallic chemistry 694.23(2009):3742-3748. |
入库方式： OAI收割
来源：长春应用化学研究所
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