Near-infrared luminescent properties and natural lifetime calculation of a novel Er3+ complex
文献类型：期刊论文
| 作者 | Li XY ; Si ZJ ; Pan CL ; Zhou L ; Li ZF ; Li XN ; Tang JK ; Zhang HJ |
| 刊名 | inorganic chemistry communications
 |
| 出版日期 | 2009 |
| 卷号 | 12期号:7页码:675-677 |
| 关键词 | INTRAMOLECULAR ENERGY TRANSFER RARE-EARTH IONS LANTHANIDE COMPLEXES ERBIUM COMPLEX DONOR LIGANDS MU-M STATE INTENSITIES ABSORPTION CHEMISTRY |
| ISSN号 | 1387-7003 |
| 通讯作者 | zhang hj |
| 中文摘要 | in this communication, a novel er3+ complex er(pt)(3)tppo [pt = 1-phenyl-3-methyl-4-tert-butylbenzoyl-5-pyrazolone, tppo = triphenyl phosphine oxide] is successfully synthesized and characterized by elemental analysis and single-crystal x-ray diffraction. its optical properties and the energy transfer process from the ligand pt to the er3+ ion are investigated, the typical near-infrared (nir) luminescence (centered at around 1530 nm) is attributed to the i-4(13/2) -> i-4(15/2) transition of er3+ ion which results from the efficient energy transfer from pt to er3+ ion (an antenna effect). the wider full width at half maximum (78 nm) peaked at 1530 nm in the emission spectrum and the judd-ofelt theory calculation on the radiative properties suggest that er(pt)(3)tppo should be a promising candidate for tunable lasers and planar optical amplifiers. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000268562800025 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/11373]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li XY,Si ZJ,Pan CL,et al. Near-infrared luminescent properties and natural lifetime calculation of a novel Er3+ complex[J]. inorganic chemistry communications,2009,12(7):675-677. |
| APA | Li XY.,Si ZJ.,Pan CL.,Zhou L.,Li ZF.,...&Zhang HJ.(2009).Near-infrared luminescent properties and natural lifetime calculation of a novel Er3+ complex.inorganic chemistry communications,12(7),675-677. |
| MLA | Li XY,et al."Near-infrared luminescent properties and natural lifetime calculation of a novel Er3+ complex".inorganic chemistry communications 12.7(2009):675-677. |
入库方式： OAI收割
来源：长春应用化学研究所
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