Metal dependent control of cis-/trans-1,4 regioselectivity in 1,3-butadiene polymerization catalyzed by transition metal complexes supported by 2,6-bis[1-(iminophenyl)ethyl]pyridine
文献类型：期刊论文
| 作者 | Gong DR ; Wang BL ; Bai CX ; Bi JF ; Wang F ; Dong WM ; Zhang XQ ; Jiang LS |
| 刊名 | polymer
 |
| 出版日期 | 2009 |
| 卷号 | 50期号:26页码:6259-6264 |
| 关键词 | ALLYL-INSERTION MECHANISM LINEAR ALPHA-OLEFINS O-DONATED LIGANDS BUTADIENE POLYMERIZATION ETHYLENE POLYMERIZATION SYNDIOTACTIC 1 1 LIVING POLYMERIZATION COBALT(II) COMPLEXES MOLECULAR-WEIGHT 2-POLYBUTADIENE 3-DIENE POLYMERIZATION |
| ISSN号 | 0032-3861 |
| 通讯作者 | zhang xq |
| 中文摘要 | fe(iii), cr(iii), fe(ii), co(ii) and ni(ii) chloride complexes supported by 2,6-bis[1-(iminophenyl)ethyl]pyridine have been synthesized and characterized along with single crystal x-ray diffraction. these complexes, in combination with mao, have been examined in butadiene polymerization. the catalytic activity and regioselectivity are strongly controlled by metal center and cocatalyst (mao/co ratio dependent in the case of co(ii) complex). the activity decreases in the order of fe(iii) > co(ii) > cr(iii) approximate to ni (ii) complexes, in consistent with the space around the metal center. polybutadiene with different microstructure content, from high trans-1,4 units (88-95% for iron(iii) and cr(iii)), medium trans-1,4 and cis-1,4 units (55% and 35%, respectively, for iron(ii)) to high cis-1,4 units 79% for co(ii) and 97% for ni(ii) call be easily achieved by varying of the metal center. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272654100010 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://202.98.16.49/handle/322003/11413]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Gong DR,Wang BL,Bai CX,et al. Metal dependent control of cis-/trans-1,4 regioselectivity in 1,3-butadiene polymerization catalyzed by transition metal complexes supported by 2,6-bis[1-(iminophenyl)ethyl]pyridine[J]. polymer,2009,50(26):6259-6264. |
| APA | Gong DR.,Wang BL.,Bai CX.,Bi JF.,Wang F.,...&Jiang LS.(2009).Metal dependent control of cis-/trans-1,4 regioselectivity in 1,3-butadiene polymerization catalyzed by transition metal complexes supported by 2,6-bis[1-(iminophenyl)ethyl]pyridine.polymer,50(26),6259-6264. |
| MLA | Gong DR,et al."Metal dependent control of cis-/trans-1,4 regioselectivity in 1,3-butadiene polymerization catalyzed by transition metal complexes supported by 2,6-bis[1-(iminophenyl)ethyl]pyridine".polymer 50.26(2009):6259-6264. |
入库方式： OAI收割
来源：长春应用化学研究所
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