Determination of isocyanates by capillary electrophoresis with tris(2,2 '-bipyridine) ruthenium(II) electrochemiluminescence
文献类型：期刊论文
| 作者 | Li HJ ; Shi LH ; Liu XQ ; Niu WX ; Xu GB |
| 刊名 | electrophoresis
 |
| 出版日期 | 2009 |
| 卷号 | 30期号:22页码:3926-3931 |
| 关键词 | SOLID-STATE ELECTROCHEMILUMINESCENCE ELECTROGENERATED CHEMI-LUMINESCENCE PERFORMANCE LIQUID-CHROMATOGRAPHY COMPOSITE FILMS TERTIARY-AMINES HEXAMETHYLENE DIISOCYANATE AIRBORNE ISOCYANATES ZONE-ELECTROPHORESIS AQUEOUS-SOLUTION ULTRATHIN FILMS |
| ISSN号 | 0173-0835 |
| 通讯作者 | xu gb |
| 中文摘要 | ce with tris(2,2'-bipyridyl) ruthenium(ii) (ru(bpy)(3)(2+)) electrochemiluminescence (ecl) detection for the quantitative determination of isocyanates was first reported. hexamethylene diisocyanate (hdi) and hexyl isocyanate (hi) were used as the model analytes. commercially available n,n-diethyl-n'-methylethylenediamine was used as the derivatization reagent. it has both a secondary amine group and a tertiary amine group. the secondary amine group can quantitatively react with isocyanate group, and the tertiary amine group can react with ru(bpy)(3)(2+) to produce strong ecl signal for sensitive detection. the derivatization reaction was almost instantaneous and is much faster than other reported derivative reactions using other derivative reagents. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272474900017 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/11423]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li HJ,Shi LH,Liu XQ,et al. Determination of isocyanates by capillary electrophoresis with tris(2,2 '-bipyridine) ruthenium(II) electrochemiluminescence[J]. electrophoresis,2009,30(22):3926-3931. |
| APA | Li HJ,Shi LH,Liu XQ,Niu WX,&Xu GB.(2009).Determination of isocyanates by capillary electrophoresis with tris(2,2 '-bipyridine) ruthenium(II) electrochemiluminescence.electrophoresis,30(22),3926-3931. |
| MLA | Li HJ,et al."Determination of isocyanates by capillary electrophoresis with tris(2,2 '-bipyridine) ruthenium(II) electrochemiluminescence".electrophoresis 30.22(2009):3926-3931. |
入库方式： OAI收割
来源：长春应用化学研究所
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