Synthesis and characterization of phenylene-thiophene all-conjugated diblock copolymers
文献类型：期刊论文
| 作者 | Wu SP ; Bu LJ ; Huang L ; Yu XH ; Han YC ; Geng YH ; Wang FS |
| 刊名 | polymer
 |
| 出版日期 | 2009 |
| 卷号 | 50期号:26页码:6245-6251 |
| 关键词 | CATALYST-TRANSFER POLYCONDENSATION BLOCK-COPOLYMERS REGIOREGULAR POLY(3-HEXYLTHIOPHENE) FACILE SYNTHESIS CONDENSATION POLYMERIZATION MICROPHASE SEPARATION SOLAR-CELLS POLYMERS POLY(P-PHENYLENE) FUNCTIONALIZATION |
| ISSN号 | 0032-3861 |
| 通讯作者 | geng yh |
| 中文摘要 | grignard metathesis (grim) polymerization for all-conjugated diblock copolymers comprising poly (2,5-dihexyloxy-1,4-phenylene) (ppp) and poly(3-hexylthiophene) (p3ht) blocks were systematically studied with licl as additive and 1,2-bis (diphenylphosphino) ethane nickel dichloride (ni(dppe)cl-2) or 1,3-bis(diphenylphosphino) propane nickel dichloride (ni(dppp)cl-2) as catalyst. it was found that the addition order of the monomers was crucial for the success of copolymerization. with the monomer addition in the order of phenyl and then thienyl grignard reagents, all-conjugated ppp-b-p3ht diblock copolymers with different block ratios were successfully synthesized. in contrast, the inverted addition order only afforded a mixture containing both block copolymers and deactivated or end-capped homopolymers. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272654100008 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://202.98.16.49/handle/322003/11453]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu SP,Bu LJ,Huang L,et al. Synthesis and characterization of phenylene-thiophene all-conjugated diblock copolymers[J]. polymer,2009,50(26):6245-6251. |
| APA | Wu SP.,Bu LJ.,Huang L.,Yu XH.,Han YC.,...&Wang FS.(2009).Synthesis and characterization of phenylene-thiophene all-conjugated diblock copolymers.polymer,50(26),6245-6251. |
| MLA | Wu SP,et al."Synthesis and characterization of phenylene-thiophene all-conjugated diblock copolymers".polymer 50.26(2009):6245-6251. |
入库方式： OAI收割
来源：长春应用化学研究所
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