Effect of hydroxyl and amino groups on electrochemiluminescence activity of tertiary amines at low tris(2,2 '-bipyridyl)ruthenium(II) concentrations
文献类型：期刊论文
| 作者 | Han S ; Niu WX ; Li HJ ; Hu LZ ; Yuan YL ; Xu GB |
| 刊名 | talanta
 |
| 出版日期 | 2010 |
| 卷号 | 81期号:1-2页码:44-47 |
| 关键词 | INHIBITED RU(BPY)(3)(2+) ELECTROCHEMILUMINESCENCE ELECTROGENERATED CHEMILUMINESCENCE EMISSION INTENSITY LIGHT-EMISSION ECL REACTION SYSTEM OXIDATION DNA TRIS(2 RUTHENIUM(II) 2'-BIPYRIDINE)RUTHENIUM(II) |
| ISSN号 | 0039-9140 |
| 通讯作者 | xu gb |
| 中文摘要 | ecl of several amines containing different numbers of hydroxyl and amino groups was investigated. n-butyldiethanolamine is found to be more effective than 2-(dibutylamino)ethanol at gold and platinum electrodes, and is the most effective coreactant reported until now. surprisingly, ecl intensities of monoamines, such as 2-(dibutylamino)ethanol and n-butyldiethanolamine, are much stronger than that of diamines including n,n,n',n'-tetrakis-(2-hydroxyethyl)-ethylenediamine and n,n,n',n'-tetrakis-(2-hydroxypropyl)ethlenediamine. the striking contrast between ecl signals of the investigated monoamines and diamines may result from more significant side reactions of diamines, such as the intramolecular side reactions between oxidative amine cation radicals and reductive amine free radicals. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000276052700008 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://202.98.16.49/handle/322003/11471]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Han S,Niu WX,Li HJ,et al. Effect of hydroxyl and amino groups on electrochemiluminescence activity of tertiary amines at low tris(2,2 '-bipyridyl)ruthenium(II) concentrations[J]. talanta,2010,81(1-2):44-47. |
| APA | Han S,Niu WX,Li HJ,Hu LZ,Yuan YL,&Xu GB.(2010).Effect of hydroxyl and amino groups on electrochemiluminescence activity of tertiary amines at low tris(2,2 '-bipyridyl)ruthenium(II) concentrations.talanta,81(1-2),44-47. |
| MLA | Han S,et al."Effect of hydroxyl and amino groups on electrochemiluminescence activity of tertiary amines at low tris(2,2 '-bipyridyl)ruthenium(II) concentrations".talanta 81.1-2(2010):44-47. |
入库方式： OAI收割
来源：长春应用化学研究所
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