Nucleation in A/B/AB blends: Interplay between microphase assembly and macrophase separation
文献类型：期刊论文
| 作者 | Wang JF ; Muller M ; Wang ZG |
| 刊名 | journal of chemical physics
 |
| 出版日期 | 2009 |
| 卷号 | 130期号:15页码:文献编号：154902 |
| 关键词 | SELF-CONSISTENT-FIELD COPOLYMER-HOMOPOLYMER BLENDS MONTE-CARLO-SIMULATION BINARY POLYMER BLENDS DIBLOCK COPOLYMERS INTERFACIAL CURVATURE PHASE-BEHAVIOR BICONTINUOUS MICROEMULSIONS REPULSIVE INTERACTIONS BLOCK-COPOLYMERS |
| ISSN号 | 0021-9606 |
| 通讯作者 | wang jf |
| 中文摘要 | we study the interplay between microphase assembly and macrophase separation in a/b/ab ternary polymer blends by examining the free energy of localized fluctuation structures (micelles or droplets), with emphasis on the thermodynamic relationship between swollen micelles (microemulsion) and the macrophase-separated state, using self-consistent field theory and an extended capillary model. upon introducing homopolymer b into a micelle-forming binary polymer blend a/ab, micelles can be swollen by b. a small amount of component b (below the a-rich binodal of macrophase coexistence) will not affect the stability of the swollen micelles. a large excess of homopolymer, b, will induce a microemulsion failure and lead to a macrophase separation. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000265486300041 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://202.98.16.49/handle/322003/11549]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang JF,Muller M,Wang ZG. Nucleation in A/B/AB blends: Interplay between microphase assembly and macrophase separation[J]. journal of chemical physics,2009,130(15):文献编号：154902. |
| APA | Wang JF,Muller M,&Wang ZG.(2009).Nucleation in A/B/AB blends: Interplay between microphase assembly and macrophase separation.journal of chemical physics,130(15),文献编号：154902. |
| MLA | Wang JF,et al."Nucleation in A/B/AB blends: Interplay between microphase assembly and macrophase separation".journal of chemical physics 130.15(2009):文献编号：154902. |
入库方式： OAI收割
来源：长春应用化学研究所
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