中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A novel technique for NACE coupled with simultaneous electrochemiluminescence and electrochemical detection for fast analysis of tertiary amines

文献类型:期刊论文

作者Yuan BQ ; Huang JS ; Sun JY ; You TY
刊名electrophoresis
出版日期2009
卷号30期号:3页码:479-486
关键词CAPILLARY-ZONE-ELECTROPHORESIS MICELLAR ELECTROKINETIC CHROMATOGRAPHY POROUS ETCHED JOINT DUAL-ELECTRODE ELECTROGENERATED CHEMILUMINESCENCE DETECTION SYSTEM LIGHT-EMISSION DETECTION CELL MICROCHIP ACIDS
ISSN号0173-0835
通讯作者you ty
中文摘要a simultaneous electrochemiluminescence (ecl) and electrochemical (ec) detection scheme for nace was presented for fast analysis of tertiary amines. both ecl and ec signals were generated at the same pt electrode. triethylamine (tea), tripropylamine (tpra), chlorpromazine, promethazine, and dioxopromethazine (dpz) were selected to validate nace-ecl/ec dual detection strategy. the linear ranges for tea and tpra were 0.01-500 and 0.01-10 mu m with the detection limits of 8.0 and 5.0 nm (s/n=3), respectively. the rsds (n = 6) of the migration time and the ecl intensity for 1 mu m tea and 0.5 mu m tpra were 0.1 and 2.8%, and 0.2 and 1.8% with theoretical plate numbers of 180 000 and 700 000 per meter, respectively. these two analytes could be separated within 92 s and the pt electrode did not need reactivation during the experiments.
收录类别SCI
语种英语
WOS记录号WOS:000264357500007
公开日期2010-05-04
源URL[http://202.98.16.49/handle/322003/11653]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Yuan BQ,Huang JS,Sun JY,et al. A novel technique for NACE coupled with simultaneous electrochemiluminescence and electrochemical detection for fast analysis of tertiary amines[J]. electrophoresis,2009,30(3):479-486.
APA Yuan BQ,Huang JS,Sun JY,&You TY.(2009).A novel technique for NACE coupled with simultaneous electrochemiluminescence and electrochemical detection for fast analysis of tertiary amines.electrophoresis,30(3),479-486.
MLA Yuan BQ,et al."A novel technique for NACE coupled with simultaneous electrochemiluminescence and electrochemical detection for fast analysis of tertiary amines".electrophoresis 30.3(2009):479-486.

入库方式: OAI收割

来源:长春应用化学研究所

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