中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A novel tris(2,2 '-bipyridine)ruthenium(II)/tripropylamine cathodic electrochemiluminescence in acetonitrile for the indirect determination of hydrogen peroxide

文献类型:期刊论文

作者Yuan BQ ; Du HW ; You TY
刊名talanta
出版日期2009
卷号79期号:3页码:730-733
关键词ELECTROGENERATED CHEMI-LUMINESCENCE AQUEOUS-SOLUTION ELECTROCHEMICAL DETECTION SENSING APPLICATION CHEMILUMINESCENCE ELECTRODES SYSTEM RU(BPY)(3)(2+) NANOTUBES SENSOR
ISSN号0039-9140
通讯作者you ty
中文摘要a novel tris(2,2'-bipyridine)ruthenium(ii) (ru(bpy)3(2+)) cathodic electrochemiluminescence (ecl) was generated at -0.78v at the pt electrode in acetonitrile (acn), which suggested that the cathodic ecl differed from conventional cathodic ecl it was found that tripropylamine (tpra) could enhance this cathodic ecl and the linear range (log-log plot) was 0.2 mu m-0.2 mm. in addition, hydrogen peroxide (h2o2) could inhibit the cathodic ecl and was indirectly detected with the linear range of 27-540 mu m. the rsd (n = 12) of the ecl intensity in the presence of 135 mu m h2o2 was 0.87%. this method was also demonstrated for the fast determination of h2o2 in disinfectant sample and satisfactory results were obtained.
收录类别SCI
语种英语
WOS记录号WOS:000268346800026
公开日期2010-05-04
源URL[http://202.98.16.49/handle/322003/11655]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Yuan BQ,Du HW,You TY. A novel tris(2,2 '-bipyridine)ruthenium(II)/tripropylamine cathodic electrochemiluminescence in acetonitrile for the indirect determination of hydrogen peroxide[J]. talanta,2009,79(3):730-733.
APA Yuan BQ,Du HW,&You TY.(2009).A novel tris(2,2 '-bipyridine)ruthenium(II)/tripropylamine cathodic electrochemiluminescence in acetonitrile for the indirect determination of hydrogen peroxide.talanta,79(3),730-733.
MLA Yuan BQ,et al."A novel tris(2,2 '-bipyridine)ruthenium(II)/tripropylamine cathodic electrochemiluminescence in acetonitrile for the indirect determination of hydrogen peroxide".talanta 79.3(2009):730-733.

入库方式: OAI收割

来源:长春应用化学研究所

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