Novel hydrophilic-hydrophobic multiblock copolyimides as proton exchange membranes: Enhancing the proton conductivity
文献类型:期刊论文
作者 | Li NW ; Liu J ; Cui ZM ; Zhang SB ; Xing W |
刊名 | polymer
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出版日期 | 2009 |
卷号 | 50期号:19页码:4505-4511 |
关键词 | FUEL-CELL APPLICATIONS POLYMER ELECTROLYTE MEMBRANES POLY(ARYLENE ETHER SULFONE) POLYSULFONE IONOMERS BLOCK-COPOLYMERS SIDE-CHAINS POLYIMIDES MORPHOLOGY TRANSPORT TRIBLOCK |
ISSN号 | 0032-3861 |
通讯作者 | zhang sb |
中文摘要 | a series of novel multiblock copolymers based on sulfonated copolyimides were developed and evaluated for use as proton exchange membranes (pems). in these multiblock copolyimides, the hydrophilic blocks were composed of the sulfonated dianhydride and the sulfonated diamine, with sulfonic acid groups on every aromatic ring (i.e., fully sulfonated). this molecular design was implemented to effectively enhance the proton conductivity. the properties of the multiblock copolyimides with varying iec values or block lengths were investigated to obtain a better understanding of the relationship between molecular structure and properties of proton exchange membranes. the water uptake and proton conductivity were found to be highly dependent upon their structure. the block copolymers displayed significantly higher proton conductivities, especially at low relative humidity than the random copolymers with a similar iec. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000272959200013 |
公开日期 | 2010-05-04 |
源URL | [http://202.98.16.49/handle/322003/11677] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Li NW,Liu J,Cui ZM,et al. Novel hydrophilic-hydrophobic multiblock copolyimides as proton exchange membranes: Enhancing the proton conductivity[J]. polymer,2009,50(19):4505-4511. |
APA | Li NW,Liu J,Cui ZM,Zhang SB,&Xing W.(2009).Novel hydrophilic-hydrophobic multiblock copolyimides as proton exchange membranes: Enhancing the proton conductivity.polymer,50(19),4505-4511. |
MLA | Li NW,et al."Novel hydrophilic-hydrophobic multiblock copolyimides as proton exchange membranes: Enhancing the proton conductivity".polymer 50.19(2009):4505-4511. |
入库方式: OAI收割
来源:长春应用化学研究所
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