Highly Active Carbon-supported PdSn Catalysts for Formic Acid Electrooxidation
文献类型:期刊论文
作者 | Zhang ZH ; Ge JJ ; Ma LA ; Liao JH ; Lu TH ; Xing W |
刊名 | fuel cells
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出版日期 | 2009 |
卷号 | 9期号:2页码:114-120 |
关键词 | NOBLE-METAL ELECTRODES FUEL-CELLS METHANOL ELECTROOXIDATION ETHANOL OXIDATION CHEMICAL-COMPOSITION PLATINUM-ELECTRODES PALLADIUM ELECTROCATALYSTS REDUCTION NANOPARTICLES |
ISSN号 | 1615-6846 |
通讯作者 | xing w |
中文摘要 | pdsn/c catalysts with different atomic ratios of pd to sn were synthesised by a nabh4 reduction method. electrochemical tests show that the alloy catalysts exhibit significantly higher catalytic activity and stability for formic acid electrooxidation (faeo) than the pd/c catalyst prepared with the same method. xrd and tem indicate that a particle-size effect is not the main cause for the high performance. xps confirms that pd is modified by sn through an electronic effect which can decrease the adsorption strength of poisonous intermediates on pd and thus promote the faeo greatly. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000265796900003 |
公开日期 | 2010-05-04 |
源URL | [http://ir.ciac.jl.cn/handle/322003/11717] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang ZH,Ge JJ,Ma LA,et al. Highly Active Carbon-supported PdSn Catalysts for Formic Acid Electrooxidation[J]. fuel cells,2009,9(2):114-120. |
APA | Zhang ZH,Ge JJ,Ma LA,Liao JH,Lu TH,&Xing W.(2009).Highly Active Carbon-supported PdSn Catalysts for Formic Acid Electrooxidation.fuel cells,9(2),114-120. |
MLA | Zhang ZH,et al."Highly Active Carbon-supported PdSn Catalysts for Formic Acid Electrooxidation".fuel cells 9.2(2009):114-120. |
入库方式: OAI收割
来源:长春应用化学研究所
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