Effect of Copolymerization Time on the Microstructure and Properties of Polypropylene/Poly(ethylene-co-propylene) In-Reactor Alloys
文献类型：期刊论文
| 作者 | Fan YD ; Zhang CY ; Xue YH ; Nie W ; Zhang XQ ; Ji XL ; Bo SQ |
| 刊名 | polymer journal
 |
| 出版日期 | 2009 |
| 卷号 | 41期号:12页码:1098-1104 |
| 关键词 | ZIEGLER-NATTA CATALYST MECHANICAL-PROPERTIES CHAIN STRUCTURE ISOTACTIC POLYPROPYLENE BLOCK-COPOLYMER SITU BLENDS GAS-PHASE PROPYLENE MORPHOLOGY ETHYLENE |
| ISSN号 | 0032-3896 |
| 通讯作者 | ji xl |
| 中文摘要 | three polypropylene/poly(ethylene-co-propylene) (pp/epr) in-reactor alloys produced by a two-stage slurry/gas polymerization had different ethylene contents and mechanical properties, which were achieved by controlling the copolymerization time. the three alloys were fractionated into five fractions via temperature rising dissolution fractionation (trdf), respectively. the chain structures of the whole samples and their fractions were analyzed using high-temperature gel permeation chromatography (gpc), fourier transform infrared (ft-ir), c-13 nuclear magnetic resonance (c-13 nmr), and differential scanning calorimetry (dsc) techniques. these three in-reactor alloys mainly contained four portions: ethylenepropylene random copolymer (epr), ethylene-propylene (ep) segmented and block copolymers, and propylene homopolymer. the increased copolymerization time caused the increased ethylene content of the sample. the weight percent of epr, ep segmented and block copolymer also became higher. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272990800013 |
| 公开日期 | 2010-05-04 |
| 源URL | [http://202.98.16.49/handle/322003/11813]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Fan YD,Zhang CY,Xue YH,et al. Effect of Copolymerization Time on the Microstructure and Properties of Polypropylene/Poly(ethylene-co-propylene) In-Reactor Alloys[J]. polymer journal,2009,41(12):1098-1104. |
| APA | Fan YD.,Zhang CY.,Xue YH.,Nie W.,Zhang XQ.,...&Bo SQ.(2009).Effect of Copolymerization Time on the Microstructure and Properties of Polypropylene/Poly(ethylene-co-propylene) In-Reactor Alloys.polymer journal,41(12),1098-1104. |
| MLA | Fan YD,et al."Effect of Copolymerization Time on the Microstructure and Properties of Polypropylene/Poly(ethylene-co-propylene) In-Reactor Alloys".polymer journal 41.12(2009):1098-1104. |
入库方式： OAI收割
来源：长春应用化学研究所
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