Synthesis, crystal structures and spectroscopic properties of copper(I) complexes containing beta-dialdiminato supporting ligands
文献类型：期刊论文
| 作者 | Li XW ; Ding JQ ; Jin WQ ; Cheng YX |
| 刊名 | inorganica chimica acta
 |
| 出版日期 | 2009 |
| 卷号 | 362期号:1页码:233-237 |
| 关键词 | CU-I COMPLEXES EMITTING ELECTROCHEMICAL-CELLS DIKETIMINATE LIGANDS REACTIVITY MONONUCLEAR CHEMISTRY DIODES CU(I) |
| ISSN号 | 0020-1693 |
| 通讯作者 | cheng yx |
| 中文摘要 | two mononuclear neutral copper(i) complexes, cu(l-1)pph3 (1), cu(l-2)(pph3)(2) (2) ([l-1](-) = [{n((c6h3pr2)-pr-i-2,6)c(h)}(2)cph](-); [l-2](-) = [{n(c6h5)c(h)}(2)cph](-)) have been synthesized and structurally characterized by x-ray crystallography. in complex 1, the copper(i) atom is in a distorted three-coordinate trigonal planar environment, whereas in complex 2 with the less sterically hindered beta-dialdiminato ligand, the copper(i) atom is the centre of a four-coordinate distorted tetrahedron. at room temperature complexes 1 and 2 in a film of pmma exhibit green emission at 543 and 549 nm with lifetimes of 5.28 and 5.32 ns, respectively. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000261274400034 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/11831]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li XW,Ding JQ,Jin WQ,et al. Synthesis, crystal structures and spectroscopic properties of copper(I) complexes containing beta-dialdiminato supporting ligands[J]. inorganica chimica acta,2009,362(1):233-237. |
| APA | Li XW,Ding JQ,Jin WQ,&Cheng YX.(2009).Synthesis, crystal structures and spectroscopic properties of copper(I) complexes containing beta-dialdiminato supporting ligands.inorganica chimica acta,362(1),233-237. |
| MLA | Li XW,et al."Synthesis, crystal structures and spectroscopic properties of copper(I) complexes containing beta-dialdiminato supporting ligands".inorganica chimica acta 362.1(2009):233-237. |
入库方式： OAI收割
来源：长春应用化学研究所
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