Synthesis, characterization and electrophosphorescent properties of mononuclear platinum(II) complexes based on 2-phenylbenzoimidazole derivatives
文献类型:期刊论文
作者 | Li H ; Ding JQ ; Xie ZY ; Cheng YX ; Wang LX |
刊名 | journal of organometallic chemistry
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出版日期 | 2009 |
卷号 | 694期号:17页码:2777-2785 |
关键词 | ORGANIC ELECTROLUMINESCENT DEVICES CYCLOMETALATED IRIDIUM COMPLEXES LIGHT-EMITTING-DIODES CENTER-DOT-PT HIGH-EFFICIENCY PHOSPHORESCENT MATERIALS CRYSTAL-STRUCTURE TRIPLET EMITTERS LIGANDS EMISSION |
ISSN号 | 0022-328x |
通讯作者 | cheng yx |
中文摘要 | the rational design, synthesis and characterization of five phosphorescent platinum complexes [(c boolean and n) pt(acac)] [hacac = acetylacetone, hc boolean and n = 1-methyl-2-(4-fluorophenyl)benzoimidazole (h-fmbi), 1-methyl-2-phenylbenzoimidazole (h-mbi), 1,2-diphenyl-benzoimidazole (h-pbi), 1-(4-(3,6-di-t-butylcarbazol-9-yl)) phenyl-2-phenylbenzoimidazole (t-bucz-h-pbi), and 1-(4-(3,6-di-(3,6-di-t-butyl-carbazol-9-yl))carbazol-9-yl) phenyl-2-phenylbenzoimidazole (t-buczcz-h-pbi)] have been discussed. the crystal structure of (mbi) pt(acac) shows a nearly ideal square planar geometry around pt atom and the weak intermolecular interactions with pi-pi spacing of 3.55 angstrom. all of the complexes emit green phosphorescence from the metal-to-ligand charge-transfer (mlct) excited state with high quantum efficiency (0.08-0.17) at room temperature. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000267931300017 |
公开日期 | 2010-05-27 |
源URL | [http://202.98.16.49/handle/322003/11839] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Li H,Ding JQ,Xie ZY,et al. Synthesis, characterization and electrophosphorescent properties of mononuclear platinum(II) complexes based on 2-phenylbenzoimidazole derivatives[J]. journal of organometallic chemistry,2009,694(17):2777-2785. |
APA | Li H,Ding JQ,Xie ZY,Cheng YX,&Wang LX.(2009).Synthesis, characterization and electrophosphorescent properties of mononuclear platinum(II) complexes based on 2-phenylbenzoimidazole derivatives.journal of organometallic chemistry,694(17),2777-2785. |
MLA | Li H,et al."Synthesis, characterization and electrophosphorescent properties of mononuclear platinum(II) complexes based on 2-phenylbenzoimidazole derivatives".journal of organometallic chemistry 694.17(2009):2777-2785. |
入库方式: OAI收割
来源:长春应用化学研究所
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