Synthesis, photophysical and electrophosphorescent properties of mononuclear Pt(II) complexes with arylamine functionalized cyclometalating ligands
文献类型：期刊论文
| 作者 | Qiu DF ; Wu J ; Xie ZY ; Cheng YX ; Wang LX |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 694期号:5页码:737-746 |
| 关键词 | LIGHT-EMITTING DEVICES BOOLEAN-AND-C COORDINATED PLATINUM(II) COMPLEXES PALLADIUM-CATALYZED SYNTHESIS PI-PI INTERACTIONS ELECTRONIC SPECTROSCOPY EMISSION ABSORPTION BINUCLEAR POLYMERS |
| ISSN号 | 0022-328x |
| 通讯作者 | cheng yx |
| 中文摘要 | four cyclometalated pt(ii) complexes, i.e., [(l-2)ptcl] (1b), [(l-3)ptcl] (1c), [(l-2)ptc cc6h5] (2b) and [(l-3)ptc cc6h5] (2c) (hl2 = 4-[p-(n-butyl-n-phenyl)anilino]-6-phenyl-2,2'-bipyridine and hl3 = 4-[p(-n,n'-dibutyl-n'-phenyl)phenylene-diamino]-phenyl-6-phenyl-2,2'-bipyridine), have been synthesized and verified by h-1 nmr, c-13 nmr and x-ray crystallography. unlike previously reported complexes [(l-1)ptcl] (1a) and [(l-1)ptc cc6h5] (2a) (hl1 = 4,6-diphenyl-2,2'-bipyridine), intense and continuous absorption bands in the region of 300-500 nm with strong metal-to-ligand charge transfer ((mlct)-m-1) (d pi(pt) -> pi*(l)) transitions (epsilon similar to 2 x 10(4) dm(3) mol (1) cm (1)) at 449-467 nm were observed in the uv-vis absorption spectra of complexes 1b, 1c, 2b and 2c. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000263365600020 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/11841]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Qiu DF,Wu J,Xie ZY,et al. Synthesis, photophysical and electrophosphorescent properties of mononuclear Pt(II) complexes with arylamine functionalized cyclometalating ligands[J]. journal of organometallic chemistry,2009,694(5):737-746. |
| APA | Qiu DF,Wu J,Xie ZY,Cheng YX,&Wang LX.(2009).Synthesis, photophysical and electrophosphorescent properties of mononuclear Pt(II) complexes with arylamine functionalized cyclometalating ligands.journal of organometallic chemistry,694(5),737-746. |
| MLA | Qiu DF,et al."Synthesis, photophysical and electrophosphorescent properties of mononuclear Pt(II) complexes with arylamine functionalized cyclometalating ligands".journal of organometallic chemistry 694.5(2009):737-746. |
入库方式： OAI收割
来源：长春应用化学研究所
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