The Study of Electroactive Block Copolymer Containing Aniline Pentamer Isolated from Different Solvents
文献类型：期刊论文
| 作者 | Hu J ; Huang LH ; Lang L ; Liu YD ; Zhuang XL ; Chen XS ; Wei Y ; Jing XB |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 47期号:5页码:1298-1307 |
| 关键词 | CONJUGATED POLYMERS POLYANILINE WATER ROD |
| ISSN号 | 0887-624x |
| 通讯作者 | chen xs |
| 中文摘要 | for the films and powder of polymers containing conductive oligomer are usually obtained from solution, the choice of better solvents for the regular arrangement of oligomers is very important for the higher conductivity. because of the poor solubility of the oligomers, it is difficult to study the arrangement directly in most common solvents, so, we synthesized a triblock copolymer, mpeg2k-aniline pentamer-mpeg2k, as the model to investigate the arrangement-solvent relationship. for the poor solubility of the ap block in common solvents, the copolymer self-assembled into spheric micelles in toluene and into lamellar crystals in water and thf. the crystallinity (x-c) and crystallization temperature (t-c) values of mpeg blocks in powders prepared from different solvents differed obviously, which may be the effect of different self-assembled structures. from the two-phase model of one-dimensional electron density correlation function of saxs, the long period of copolymer prepared from thf was presumably equal to the long period of pure mpeg plus the chain length of ap, which demonstrates that the ap blocks arrange regularly in the noncrystalline regions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000263618100007 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/11859]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hu J,Huang LH,Lang L,et al. The Study of Electroactive Block Copolymer Containing Aniline Pentamer Isolated from Different Solvents[J]. journal of polymer science part a-polymer chemistry,2009,47(5):1298-1307. |
| APA | Hu J.,Huang LH.,Lang L.,Liu YD.,Zhuang XL.,...&Jing XB.(2009).The Study of Electroactive Block Copolymer Containing Aniline Pentamer Isolated from Different Solvents.journal of polymer science part a-polymer chemistry,47(5),1298-1307. |
| MLA | Hu J,et al."The Study of Electroactive Block Copolymer Containing Aniline Pentamer Isolated from Different Solvents".journal of polymer science part a-polymer chemistry 47.5(2009):1298-1307. |
入库方式： OAI收割
来源：长春应用化学研究所
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