Alternating Copolymerization of Carbon Dioxide and Propylene Oxide Catalyzed by Cobalt Schiff Base Complex
文献类型：期刊论文
| 作者 | Niu YS ; Li HC ; Chen XS ; Zhang WX ; Zhuang X ; Jing XB |
| 刊名 | macromolecular chemistry and physics
 |
| 出版日期 | 2009 |
| 卷号 | 210期号:15页码:1224-1229 |
| 关键词 | HYDROLYTIC KINETIC RESOLUTION CYCLOHEXENE OXIDE SALEN COMPLEXES POLY(PROPYLENE CARBONATE) TERMINAL EPOXIDES STEREOSELECTIVE POLYMERIZATION STEREOCHEMISTRY CONTROL CRYSTAL-STRUCTURE CYCLIC CARBONATE METAL-COMPLEXES |
| ISSN号 | 1022-1352 |
| 通讯作者 | chen xs |
| 中文摘要 | cobalt 2,4-dinitrophenolate (complex 1) based upon a n,n,o,o-tetradentate schiff base ligand framework was prepared. x-ray diffraction analysis confirmed that complex 1 was triclinic species with a six-coordinated central cobalt octahedron in the solid. asymmetric alternating copolymerization of carbon dioxide (co2) with racemic propylene oxide (rac-po) proceeded effectively by complex 1 in conjunction with (4-dimethylamino)pyridine (dmap), yielding a perfectly alternating and bimodal molecular weight distribution po/co2 poly(propylene carbonate) (ppc) with a small amount of cyclic carbonate byproducts. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000269175100006 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/11861]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Niu YS,Li HC,Chen XS,et al. Alternating Copolymerization of Carbon Dioxide and Propylene Oxide Catalyzed by Cobalt Schiff Base Complex[J]. macromolecular chemistry and physics,2009,210(15):1224-1229. |
| APA | Niu YS,Li HC,Chen XS,Zhang WX,Zhuang X,&Jing XB.(2009).Alternating Copolymerization of Carbon Dioxide and Propylene Oxide Catalyzed by Cobalt Schiff Base Complex.macromolecular chemistry and physics,210(15),1224-1229. |
| MLA | Niu YS,et al."Alternating Copolymerization of Carbon Dioxide and Propylene Oxide Catalyzed by Cobalt Schiff Base Complex".macromolecular chemistry and physics 210.15(2009):1224-1229. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。