Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33- Unit
文献类型：期刊论文
| 作者 | Wang ZQ ; Zhang HJ ; Wang C |
| 刊名 | inorganic chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 48期号:17页码:8180-8185 |
| 关键词 | TRANSITION-METAL-COMPLEXES SOLVOTHERMAL SYNTHESIS CRYSTAL-STRUCTURES SOLID-STATE SOLVENTOTHERMAL SYNTHESIS HYDROTHERMAL SYNTHESIS CHALCOGENIDE CLUSTERS COORDINATION POLYMERS INDIUM SULFIDES EXTENDED CHAINS |
| ISSN号 | 0020-1669 |
| 通讯作者 | zhang hj |
| 中文摘要 | four transition-metal-amine complexes incorporating indium thioarsenates with the general formula m(tren)inass4 (m=mn, co, and zn) and a noncondensed ass33- unit have been prepared and characterized. single-crystal x-ray diffraction analyses show that compound 1 (m=mn) crystallizes in the triclinic crystal system (space group: p (1) over bar) and consists of a one-dimensional (1d) inorganic (1)(infinity){[inass4](2-)} chain and [mn(tren)](2+) groups bonded to the opposite sides of an eight-membered in2as2s4 ring along the backbone of the infinite inorganic chains. compounds 2 (m=mn), 3 (m=zn), and 4 (m=co) are isomorphous molecular compounds. they all crystallize in the monoclinic crystal system (space group: p2(1)/c). the mn2+ cation of [mn(tren)](2+) in 1 has a distorted octahedral environment, while the transition-metal cations of [m(tren)](2+) in the other three compounds locate in trigonal-bipyramidal environments. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000269313500022 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/11885]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang ZQ,Zhang HJ,Wang C. Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33- Unit[J]. inorganic chemistry,2009,48(17):8180-8185. |
| APA | Wang ZQ,Zhang HJ,&Wang C.(2009).Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33- Unit.inorganic chemistry,48(17),8180-8185. |
| MLA | Wang ZQ,et al."Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33- Unit".inorganic chemistry 48.17(2009):8180-8185. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。