The synthesis and properties of meso-tetra(4-alkylamidophenyl)porphyrin liquid crystals and their Zn complexes
文献类型：期刊论文
| 作者 | Sun EJ ; Sun ZY ; Yuan M ; Wang D ; Shi TS |
| 刊名 | dyes and pigments
 |
| 出版日期 | 2009 |
| 卷号 | 81期号:2页码:124-130 |
| 关键词 | TRANSITION-METAL-COMPLEXES PHASE-TRANSITIONS PORPHYRIN DERIVATIVES BEHAVIOR |
| ISSN号 | 0143-7208 |
| 通讯作者 | shi ts |
| 中文摘要 | a series of novel, long-chain-substituted, porphyrin derivatives, meso-tetra (4-alkylamidophenyl) porphyrin ligands and their zn complexes (alkyl = 8,10,12,14,16,18) were prepared by acylation of the amino groups of 5,10,15,20-tetra(4-aminophenyl)porphyrin by alkyl chloride. mesomorphism was investigated by dsc, polarized optical microscopy (pom) and x-ray diffraction (xrd). only ligands containing chains > 12 carbon atoms displayed liquid crystalline behaviour, which exhibited a high phase transition temperature and a broad mesophase temperature span, zn complexes showed no liquid crystalline behaviour. cyclic voltammetry, luminescence spectra and surface photovoltage spectroscopy revealed that covalent linking of an alkylamido group to the tetraphenylporphyrin molecule influences, significantly, the properties of the porphyrin macrocycle. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000262186100007 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/11905]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun EJ,Sun ZY,Yuan M,et al. The synthesis and properties of meso-tetra(4-alkylamidophenyl)porphyrin liquid crystals and their Zn complexes[J]. dyes and pigments,2009,81(2):124-130. |
| APA | Sun EJ,Sun ZY,Yuan M,Wang D,&Shi TS.(2009).The synthesis and properties of meso-tetra(4-alkylamidophenyl)porphyrin liquid crystals and their Zn complexes.dyes and pigments,81(2),124-130. |
| MLA | Sun EJ,et al."The synthesis and properties of meso-tetra(4-alkylamidophenyl)porphyrin liquid crystals and their Zn complexes".dyes and pigments 81.2(2009):124-130. |
入库方式： OAI收割
来源：长春应用化学研究所
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