Integrated study on the role of solvent, catalyst and reactant in the hydrodeoxygenation of eugenol over nickel-based catalysts
文献类型：期刊论文
| 作者 | Qi, Jingbo1,2; Sung, Xianyong; Tang, Si-Fu1 ; Sun, Yuanyuan1,3; Xu, Chen1,2; Li, Xiaoyu1,2; Li, Xuebing1
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| 刊名 | APPLIED CATALYSIS A-GENERAL
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| 出版日期 | 2017-04-10 |
| 卷号 | 535页码:24-31 |
| 关键词 | Hydrodeoxygenation Eugenol Lignin Solvent Nickel-based catalyst |
| 英文摘要 | The hydrodeoxygenation (HDO) of phenols to hydrocarbons is a very promising technique process for the lignin valorization. To reveal the role of reactant, solvent and catalyst, the HDO experiments of eugenol to hydrocarbons were carried out at 523 K under 3 MPa H-2 over Ni catalysts supported on activated carbon (AC) and MFI-type zeolites in polar water and nonpolar n-hexane, respectively. It was found that Ni/AC was more efficient for the HDO of eugenol in water than in n-hexane, but Ni/HZSM-5 was just the opposite. The respective roles of Bronsted acid sites and Lewis acid sites on supports were also investigated by employing NaZSM-5, HZSM-5 and silicalite-1 as supports. It was revealed that Bronsted acid showed superior advantages (TOF: 37.9 h(-1) to 11.1 h(-1)) over Lewis acid in the dehydration of 4propyl-cyclohexanol. Oxygen-containing functional groups could be removed from the aromatic ring completely over Ni/HZSM-5 in n-hexane. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Life Sciences & Biomedicine |
| 类目[WOS] | Chemistry, Physical ; Environmental Sciences |
| 研究领域[WOS] | Chemistry ; Environmental Sciences & Ecology |
| 关键词[WOS] | AQUEOUS-PHASE HYDRODEOXYGENATION ; PHENOL HYDRODEOXYGENATION ; ETHANOL DEHYDRATION ; REACTION NETWORK ; N-PROPYLBENZENE ; MODEL COMPOUNDS ; PYROLYSIS OIL ; LEWIS ACIDITY ; LIGNIN MODEL ; GUAIACOL |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000397365100004 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9297]  |
| 专题 | 青岛生物能源与过程研究所_多相催化转化团队 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Clean & Low Carbon Energy NICE, Natl Inst, Beijing 102211, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Jingbo,Sung, Xianyong,Tang, Si-Fu,et al. Integrated study on the role of solvent, catalyst and reactant in the hydrodeoxygenation of eugenol over nickel-based catalysts[J]. APPLIED CATALYSIS A-GENERAL,2017,535:24-31. |
| APA | Qi, Jingbo.,Sung, Xianyong.,Tang, Si-Fu.,Sun, Yuanyuan.,Xu, Chen.,...&Li, Xuebing.(2017).Integrated study on the role of solvent, catalyst and reactant in the hydrodeoxygenation of eugenol over nickel-based catalysts.APPLIED CATALYSIS A-GENERAL,535,24-31. |
| MLA | Qi, Jingbo,et al."Integrated study on the role of solvent, catalyst and reactant in the hydrodeoxygenation of eugenol over nickel-based catalysts".APPLIED CATALYSIS A-GENERAL 535(2017):24-31. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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