In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries
文献类型：期刊论文
| 作者 | Chai, Jingchao1,2; Liu, Zhihong1; Ma, Jun1 ; Wang, Jia1,2; Liu, Xiaochen3; Liu, Haisheng1; Zhang, Jianjun1,2; Cui, Guanglei1; Chen, Liquan4
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| 刊名 | ADVANCED SCIENCE
 |
| 出版日期 | 2017-02-01 |
| 卷号 | 4期号:2 |
| 英文摘要 | Nowadays it is extremely urgent to seek high performance solid polymer electrolyte that possesses both interfacial stability toward lithium/graphitic anodes and high voltage cathodes for high energy density solid state batteries. Inspired by the positive interfacial effect of vinylene carbonate additive on solid electrolyte interface, a novel poly (vinylene carbonate) based solid polymer electrolyte is presented via a facile in situ polymerization process in this paper. It is manifested that poly (vinylene carbonate) based solid polymer electrolyte possess a superior electrochemical stability window up to 4.5 V versus Li/Li+ and considerable ionic conductivity of 9.82 x 10(-5) S cm(-1) at 50 degrees C. Moreover, it is demonstrated that high voltage LiCoO2/Libatteries using this solid polymer electrolyte display stable charge/discharge profiles, considerable rate capability, excellent cycling performance, and decent safety characteristic. It is believed that poly (vinylene carbonate) based electrolyte can be a very promising solid polymer electrolyte candidate for high energy density lithium batteries. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 关键词[WOS] | IONIC-CONDUCTIVITY ; ELECTROCHEMICAL PROPERTIES ; RECHARGEABLE BATTERIES ; TRANSFERENCE NUMBERS ; COMPOSITE ; SUCCINONITRILE ; CONDUCTORS ; SEPARATOR ; COMPLEXES ; MEMBRANES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000397020800016 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9302]  |
| 专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Technol Inst, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China 4.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chai, Jingchao,Liu, Zhihong,Ma, Jun,et al. In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries[J]. ADVANCED SCIENCE,2017,4(2). |
| APA | Chai, Jingchao.,Liu, Zhihong.,Ma, Jun.,Wang, Jia.,Liu, Xiaochen.,...&Chen, Liquan.(2017).In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries.ADVANCED SCIENCE,4(2). |
| MLA | Chai, Jingchao,et al."In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries".ADVANCED SCIENCE 4.2(2017). |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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