CH3NH2 gas induced (110) preferred cesium-containing perovskite films with reduced PbI6 octahedron distortion and enhanced moisture stability
文献类型:期刊论文
作者 | Chang, Yue1,3; Wang, Li2; Zhang, Jiliang4; Zhou, Zhongmin1; Li, Chongwen1; Chen, Bingbing1; Etgar, Lioz5; Cui, Guanglei1; Pang, Shuping1 |
刊名 | JOURNAL OF MATERIALS CHEMISTRY A |
出版日期 | 2017 |
卷号 | 5期号:10页码:4803-4808 |
英文摘要 | We report here the discovery of a fancy interaction between cesium iodide (CsI) and methylamine (CH3NH2) due to the presence of the hydrogen bond. The formed CsI center dot xCH(3)NH(2) is a liquid phase, which facilitates the large scale fabrication of highly uniform cesium-containing perovskite films with strong (110) preferred orientation by the CH3NH2 gas healing process. With this method, at most 10% nonpolar Cs cations could fully dope into the crystal lattice and extremely enhance the interaction of the inorganic framework with a more symmetrical PbI6 octahedron, resulting in obvious improvement in moisture stability under continuous illumination. |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
类目[WOS] | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
研究领域[WOS] | Chemistry ; Energy & Fuels ; Materials Science |
关键词[WOS] | ASSISTED SOLUTION PROCESS ; SOLAR-CELLS ; THIN-FILMS ; HALIDE PEROVSKITES ; PERFORMANCE ; EFFICIENCY ; CH(3)NH(3)PBL(3) ; EVOLUTION ; ABSORBER ; CATIONS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000396146900007 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/9323] |
专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Qingdao Univ Sci & Technol, Qingdao 266042, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100080, Peoples R China 4.City Univ Hong Kong, Dept Phys & Mat Sci, Hong Kong, Peoples R China 5.Hebrew Univ Jerusalem, Inst Chem, Casali Ctr Appl Chem, IL-91905 Jerusalem, Israel |
推荐引用方式 GB/T 7714 | Chang, Yue,Wang, Li,Zhang, Jiliang,et al. CH3NH2 gas induced (110) preferred cesium-containing perovskite films with reduced PbI6 octahedron distortion and enhanced moisture stability[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(10):4803-4808. |
APA | Chang, Yue.,Wang, Li.,Zhang, Jiliang.,Zhou, Zhongmin.,Li, Chongwen.,...&Pang, Shuping.(2017).CH3NH2 gas induced (110) preferred cesium-containing perovskite films with reduced PbI6 octahedron distortion and enhanced moisture stability.JOURNAL OF MATERIALS CHEMISTRY A,5(10),4803-4808. |
MLA | Chang, Yue,et al."CH3NH2 gas induced (110) preferred cesium-containing perovskite films with reduced PbI6 octahedron distortion and enhanced moisture stability".JOURNAL OF MATERIALS CHEMISTRY A 5.10(2017):4803-4808. |
入库方式: OAI收割
来源:青岛生物能源与过程研究所
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