Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries
文献类型：期刊论文
| 作者 | Cui, Yanyan1,2; Chai, Jingchao2,3; Du, Huiping2,3 ; Duan, Yulong2,3; Xie, Guangwen1; Liu, Zhihong2,3; Cui, Guanglei2,3
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| 刊名 | ACS APPLIED MATERIALS & INTERFACES
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| 出版日期 | 2017-03-15 |
| 卷号 | 9期号:10页码:8737-8741 |
| 关键词 | Li-ion battery poly(ethyl cyanoacrylate) in situ polymerization flexible polymer electrolytes |
| 英文摘要 | Polycyanoacrylate is a very promising matrix for polymer electrolyte, which possesses advantages of strong binding and high electrochemical stability owing to the functional nitrile groups. Herein, a facile and reliable in situ polymerization strategy of poly(ethyl cyanoacrylate) (PECA) based gel polymer electrolytes (GPE) via a high efficient anionic polymerization was introduced consisting of PECA and 4 M LiClO4 in carbonate solvents. The in situ polymerized PECA gel polymer electrolyte achieved an excellent ionic conductivity (2.7 x 10(-3) S cm(-1)) at room temperature, and exhibited a considerable electrochemical stability window up to 4.8 V vs Li/Li+. The LiFePO4/PECA-GPE/Li and LiNi1.5Mn0.5O4/PECAGPE/Li batteries using this in-situ-polymerized GPE delivered stable charge/discharge profiles, considerable rate capability, and excellent cycling performance. These results demonstrated this reliable in situ polymerization process is a very promising strategy to prepare high performance polymer electrolytes for flexible thin-film batteries, micropower lithium batteries, and deformable lithium batteries for special purpose. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Science & Technology - Other Topics ; Materials Science |
| 关键词[WOS] | ION BATTERIES ; PERFORMANCE ; PROGRESS ; MEMBRANES ; GROWTH ; CELLS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000396801200033 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9345]  |
| 专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
| 作者单位 | 1.Qingdao Univ Sci & Technol, Key Lab Nanomat, No 53 Zhengzhou Rd, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioprocess Technol, Qingdao Ind Energy Storage Res Inst, Qingdao 266101, Peoples R China 3.Univ Chinese Acad Sci, No 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Yanyan,Chai, Jingchao,Du, Huiping,et al. Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(10):8737-8741. |
| APA | Cui, Yanyan.,Chai, Jingchao.,Du, Huiping.,Duan, Yulong.,Xie, Guangwen.,...&Cui, Guanglei.(2017).Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries.ACS APPLIED MATERIALS & INTERFACES,9(10),8737-8741. |
| MLA | Cui, Yanyan,et al."Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries".ACS APPLIED MATERIALS & INTERFACES 9.10(2017):8737-8741. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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