Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst
文献类型：期刊论文
| 作者 | Hu, M. S. Liangning1; Yu, Jianqiang1; Xin, Hongchuan2; An, Zengjian2 ; Sun, Wenshou3
|
| 刊名 | CHEMISTRYSELECT
 |
| 出版日期 | 2017 |
| 卷号 | 2期号:3页码:949-952 |
| 关键词 | aerobic oxidation C-H activation halogen ions-free 2,3,6-trimethylphenol trimethyl-1,4-benzoquinone |
| 英文摘要 | A catalytic method for aerobic water-based oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone catalysed by copper(II) nitrate was achieved under mild conditions using dioxygen as an oxidant and water as a solvent. The catalyst shows high activity and selectivity in the direct oxidation of 2,3,6-trimethylphenol into trimethyl-1,4-benzoquinone. Since components used in the present system are cheap and available, our method offers a safe system in the synthesis of trimethyl-1,4-benzoquinone under halogen ions-free conditions. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | HYDROGEN-PEROXIDE ; IONIC LIQUIDS ; BENZOQUINONES ; PHENOLS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000395533100015 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9326]  |
| 专题 | 青岛生物能源与过程研究所_生物基及仿生高分子材料团队 |
| 作者单位 | 1.Qingdao Univ, Sch Chem & Chem Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China 3.Qingdao Univ, Coll Environm Sci & Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, M. S. Liangning,Yu, Jianqiang,Xin, Hongchuan,et al. Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst[J]. CHEMISTRYSELECT,2017,2(3):949-952. |
| APA | Hu, M. S. Liangning,Yu, Jianqiang,Xin, Hongchuan,An, Zengjian,&Sun, Wenshou.(2017).Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst.CHEMISTRYSELECT,2(3),949-952. |
| MLA | Hu, M. S. Liangning,et al."Aerobic Water-based Oxidation of 2,3,6-Trimethylphenol to Trimethyl-1,4-benzoquinone over Copper(II) Nitrate Catalyst".CHEMISTRYSELECT 2.3(2017):949-952. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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