Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate
文献类型：期刊论文
| 作者 | Xin, Hongchuan1; Yang, Shilei2; An, Baigang2; An, Zengjian1
|
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2017 |
| 卷号 | 7期号:22页码:13467-13472 |
| 英文摘要 | An efficient method for the selective oxychlorination of phenol to 2,4-dichlorophenol catalyzed by manganous(II) sulfate is developed using hydrogen chloride as a chlorinating source, hydrogen peroxide as an oxidant and water as a solvent. The catalyst has high activity and selectivity under mild conditions. The products are automatically isolated from aqueous solution, which also contains the catalyst at the end of the reaction, and hence product separation and catalyst recycling are both simple in this system. The performance of manganous(II) sulfate with the oxidative chlorinating system HCl/H2O2 indicates that this is a promising synthetic method for the manufacture of various 2,4-dichlorophenol derivatives. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | AROMATIC-COMPOUNDS ; CHLORINATION ; HALOGENATION ; BROMINATION ; CHLORIDE ; ACID ; ZEOLITES ; ARENES ; H2O2 ; TBHP |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000395935300055 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9329]  |
| 专题 | 青岛生物能源与过程研究所_生物基及仿生高分子材料团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Univ Sci & Technol Liaoning, Sch Chem Engn, Anshan 114051, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xin, Hongchuan,Yang, Shilei,An, Baigang,et al. Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate[J]. RSC ADVANCES,2017,7(22):13467-13472. |
| APA | Xin, Hongchuan,Yang, Shilei,An, Baigang,&An, Zengjian.(2017).Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate.RSC ADVANCES,7(22),13467-13472. |
| MLA | Xin, Hongchuan,et al."Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate".RSC ADVANCES 7.22(2017):13467-13472. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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