Synthesis, characterization, photophysics and electrophosphorescent applications of phosphorescent platinum cyclometalated complexes with 9-arylcarbazole moieties
文献类型：期刊论文
| 作者 | Ho CL ; Wong WY ; Yao B ; Xie ZY ; Wang LX ; Lin ZY |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 694期号:17页码:2735–2749 |
| 关键词 | LIGHT-EMITTING DEVICES DIIMINE DITHIOLATE COMPLEXES ELECTRON-TRANSPORTING MATERIALS HIGH-EFFICIENCY ELECTROLUMINESCENT DEVICES IRIDIUM COMPLEXES EXCITED-STATE ORGANIC ELECTROLUMINESCENT BIS(ACETYLIDE) COMPLEXES SPECTROSCOPIC PROPERTIES |
| ISSN号 | 0022-328x |
| 通讯作者 | ho cl |
| 中文摘要 | a series of cyclometalating platinum(ii) complexes with substituted 9-arylcarbazolyl chromophores have been synthesized and characterized. these complexes are thermally stable and most of them have been characterized by x-ray crystallography. the phosphorescence emissions of the complexes are dominated by (mlct)-m-3 excited states. the excited state properties of these complexes can be modulated by varying the electronic characteristics of the cyclometalating ligands via substituent effects, thus allowing the emission to be tuned from bright green to yellow, orange and red light. the correlation between the functional properties of these metallophosphors and the results of density functional theory calculations was made. because of the propensity of the electron-rich carbazolyl group to facilitate hole injection/transport, the presence of such moiety can increase the highest occupied molecular orbital levels and improve the charge balance in the resulting complexes relative to the parent platinum(ii) phosphor with 2-phenylpyridine ligand. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000267931300013 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/12045]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ho CL,Wong WY,Yao B,et al. Synthesis, characterization, photophysics and electrophosphorescent applications of phosphorescent platinum cyclometalated complexes with 9-arylcarbazole moieties[J]. journal of organometallic chemistry,2009,694(17):2735–2749. |
| APA | Ho CL,Wong WY,Yao B,Xie ZY,Wang LX,&Lin ZY.(2009).Synthesis, characterization, photophysics and electrophosphorescent applications of phosphorescent platinum cyclometalated complexes with 9-arylcarbazole moieties.journal of organometallic chemistry,694(17),2735–2749. |
| MLA | Ho CL,et al."Synthesis, characterization, photophysics and electrophosphorescent applications of phosphorescent platinum cyclometalated complexes with 9-arylcarbazole moieties".journal of organometallic chemistry 694.17(2009):2735–2749. |
入库方式： OAI收割
来源：长春应用化学研究所
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