Cinchona Alkaloid Catalyzed Enantioselective [4+2] Annulation of Allenic Esters and in Situ Generated ortho-Quinone Methides: Asymmetric Synthesis of Functionalized Chromans
文献类型：期刊论文
| 作者 | Deng, Yu-Hua1,2,3; Chu, Wen-Dao3; Zhang, Xiang-Zhi3; Yan, Xu3; Yu, Ke-Yin3; Yang, Liang-Liang3; Huang HM(黄汉民)1,2 ; Fan, Chun-An3,4
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| 刊名 | Journal of Organic Chemistry
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| 出版日期 | 2017 |
| 卷号 | 82期号:10页码:5433-5440 |
| ISSN号 | 0022-3263 |
| 通讯作者 | Fan, Chun-An |
| 英文摘要 | A novel enantioselective [4 + 2] annulation of the allenoates having a unique positive ortho-effect with in situ generated ortho-quinone methides has been developed under the catalysis of Cinchona alkaloid. This chiral amine-catalyzed reaction provides an alternative route to asymmetric catalytic construction of synthetically interesting, highly functionalized chiral chromans in good to excellent enantioselectivities (up to 97% ee). |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (21572083;21322201;21290180);the Fundamental Research Funds for the Central Universities (lzujbky-2015-48;lzujbky-2016-ct02;lzujbky-2016-ct07);the Program for Changjiang Scholars and Innovative Research Team in University (IRT_15R28);the 111 Project of the Ministry of Education of the People's Republic of China (111-2-17);the Chang Jiang Scholars Program (C-A.F.) |
| 语种 | 英语 |
| WOS记录号 | WOS:000402023200044 |
| 源URL | [http://210.77.64.217/handle/362003/21972]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, 222 Tianshui Nanlu, Lanzhou 730000, Peoples R China 4.Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng, Yu-Hua,Chu, Wen-Dao,Zhang, Xiang-Zhi,et al. Cinchona Alkaloid Catalyzed Enantioselective [4+2] Annulation of Allenic Esters and in Situ Generated ortho-Quinone Methides: Asymmetric Synthesis of Functionalized Chromans[J]. Journal of Organic Chemistry,2017,82(10):5433-5440. |
| APA | Deng, Yu-Hua.,Chu, Wen-Dao.,Zhang, Xiang-Zhi.,Yan, Xu.,Yu, Ke-Yin.,...&Fan, Chun-An.(2017).Cinchona Alkaloid Catalyzed Enantioselective [4+2] Annulation of Allenic Esters and in Situ Generated ortho-Quinone Methides: Asymmetric Synthesis of Functionalized Chromans.Journal of Organic Chemistry,82(10),5433-5440. |
| MLA | Deng, Yu-Hua,et al."Cinchona Alkaloid Catalyzed Enantioselective [4+2] Annulation of Allenic Esters and in Situ Generated ortho-Quinone Methides: Asymmetric Synthesis of Functionalized Chromans".Journal of Organic Chemistry 82.10(2017):5433-5440. |
入库方式： OAI收割
来源：兰州化学物理研究所
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