The synergy between atomically dispersed Pd and cerium oxide for enhanced catalytic properties
文献类型：期刊论文
| 作者 | Wang X(王雪)1,2; Chen, Jiayu1; Zeng, Jianxin1; Wang, Qiuxiang1; Li, Zejun3; Qin, Ruixuan1; Wu, Changzheng3; Xie, Zhaoxiong1; Zheng, Lansun1 |
| 刊名 | Nanoscale
 |
| 出版日期 | 2017 |
| 卷号 | 9期号:20页码:6643-6648 |
| ISSN号 | 2040-3364 |
| 通讯作者 | 王雪 ; Xie, Zhaoxiong |
| 英文摘要 | We report a photochemical synthesis of Pd/CeO2 catalysts with atomically dispersed Pd. Compared to atomically dispersed Pd/CeO2 with a cubic CeO2 support (Pd/CeO2-CP), atomically dispersed Pd/CeO2 with a truncated octahedral CeO2 support (Pd/CeO2-TOP) exhibited higher activity and selectivity, owing to the synergy between Pd atoms and the (111) surface of CeO2. When compared to Pd/CeO2 with Pd clusters and nanoparticles via chemical reduction, Pd/CeO2-TOP showed excellent activity with an enhancement factor of 324 in CO oxidation, as well as an activity enhancement by a factor of 344 in selective oxidation of benzyl alcohol. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Basic Research Program of China (grant no. 2015CB932301);the National Natural Science Foundation of China (grant no. 21333008) |
| 语种 | 英语 |
| WOS记录号 | WOS:000402034400004 |
| 源URL | [http://210.77.64.217/handle/362003/21988]  |
| 专题 | 兰州化学物理研究所_苏州研究院 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, P. R. China 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, P. R. China 3.Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, Hefei Science Center (CAS), and CAS Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China, Hefei, P. R. China 4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Collaborat Innovat Ctr Chem Energy Mat, Hefei Sci Ctr CAS, Hefei 230026, Peoples R China 5.Univ Sci & Technol China, CAS Key Lab Mech Behav & Design Mat, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang X,Chen, Jiayu,Zeng, Jianxin,et al. The synergy between atomically dispersed Pd and cerium oxide for enhanced catalytic properties[J]. Nanoscale,2017,9(20):6643-6648. |
| APA | Wang X.,Chen, Jiayu.,Zeng, Jianxin.,Wang, Qiuxiang.,Li, Zejun.,...&Zheng, Lansun.(2017).The synergy between atomically dispersed Pd and cerium oxide for enhanced catalytic properties.Nanoscale,9(20),6643-6648. |
| MLA | Wang X,et al."The synergy between atomically dispersed Pd and cerium oxide for enhanced catalytic properties".Nanoscale 9.20(2017):6643-6648. |
入库方式： OAI收割
来源：兰州化学物理研究所
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