Palladium Nanoparticles Immobilized on Cross-Linked Polymeric Ionic Liquid Material: Application as Efficient and Recoverable Catalyst for the Hydrogenation of Nitroarenes
文献类型:期刊论文
作者 | Jiao, Nianming; Li, Zelong; Xia CG(夏春谷)![]() ![]() |
刊名 | ChemistrySelect
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出版日期 | 2017 |
卷号 | 2期号:16页码:4545-4556 |
关键词 | Cross linked polymeric ionic liquid material Pd nanoparticles Hydrogenation Nitroarenes Heterogeneous |
ISSN号 | 2365-6549 |
通讯作者 | 刘建华 |
英文摘要 | This study offers an exclusive class of cross linked polymeric ionic liquid material poly(divinylbenzene-co-dication imidazole ionic liquids) (P(DVB-DIIL)), as a host immobilization of palladium nanoparticles (Pd NPs). The resulting P(DVB-DIIL)-Pd catalysts were fully characterized using some different techniques such as transmission electron microscopy (TEM), x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA). The immobilized palladium catalyst showed high activity for the hydrogenation of nitroarenes with H2 under mild conditions, affording the corresponding products in good to excellent yields. Moreover, the catalyst could be recovered easily and reused 10 times without significant loss of reactivity. The existence of NHC ligands in cross-linked polymeric ionic liquid material may be responsible for the formation of active and stable supported Pd NPs catalyst. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (Grant No. 21673260;21373248;21133011) |
语种 | 英语 |
WOS记录号 | WOS:000403256200036 |
源URL | [http://210.77.64.217/handle/362003/21999] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Jiao, Nianming,Li, Zelong,Xia CG,et al. Palladium Nanoparticles Immobilized on Cross-Linked Polymeric Ionic Liquid Material: Application as Efficient and Recoverable Catalyst for the Hydrogenation of Nitroarenes[J]. ChemistrySelect,2017,2(16):4545-4556. |
APA | Jiao, Nianming,Li, Zelong,Xia CG,&Liu JH.(2017).Palladium Nanoparticles Immobilized on Cross-Linked Polymeric Ionic Liquid Material: Application as Efficient and Recoverable Catalyst for the Hydrogenation of Nitroarenes.ChemistrySelect,2(16),4545-4556. |
MLA | Jiao, Nianming,et al."Palladium Nanoparticles Immobilized on Cross-Linked Polymeric Ionic Liquid Material: Application as Efficient and Recoverable Catalyst for the Hydrogenation of Nitroarenes".ChemistrySelect 2.16(2017):4545-4556. |
入库方式: OAI收割
来源:兰州化学物理研究所
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