N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates
文献类型：期刊论文
| 作者 | Jin, Liqun1,2; Hao, Wangfang1; Xu, Jianeng1; Sun N(孙楠)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Mo WM(莫卫民)1; Hu XQ(胡信全)1,2 |
| 刊名 | Chemical Communications
 |
| 出版日期 | 2017 |
| 卷号 | 53期号:29页码:4124-4127 |
| ISSN号 | 1359-7345 |
| 通讯作者 | Jin, Liqun ; 胡信全 |
| 英文摘要 | (NHC)-Cu-catalyzed C(sp)–C(sp3) bond formation has been successfully achieved under mild conditions. Nonactivated alkyl triflates, which could be easily derived from alcohols, were utilized as C–O electrophiles. Mechanistic studies suggested that copper acetylide was the active species. Scale-up reactions further demonstrated the practicality and efficiency of the developed strategy. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China (21603190;21473160;21376224);Jin alsothanks the support from Zhejiang University of Technology and Qianjiang Scholar Program funded by Zhejiang Province |
| 语种 | 英语 |
| WOS记录号 | WOS:000399728000017 |
| 源URL | [http://210.77.64.217/handle/362003/22178]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin, Liqun,Hao, Wangfang,Xu, Jianeng,et al. N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates[J]. Chemical Communications,2017,53(29):4124-4127. |
| APA | Jin, Liqun.,Hao, Wangfang.,Xu, Jianeng.,Sun N.,Hu BX.,...&Hu XQ.(2017).N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates.Chemical Communications,53(29),4124-4127. |
| MLA | Jin, Liqun,et al."N-Heterocyclic carbene copper-catalyzed direct alkylation of terminal alkynes with non-activated alkyl triflates".Chemical Communications 53.29(2017):4124-4127. |
入库方式： OAI收割
来源：兰州化学物理研究所
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