Photoluminescent Honeycomb Structures from Polyoxometalates and an Imidazolium-Based Ionic Liquid Bearing a pi-Conjugated Moiety and a Branched Aliphatic Chain
文献类型:期刊论文
作者 | Zhang, Geping1; Zhu, Hongxia1; Chen, Mengjun1; Li HG(李洪光)2; Yuan, Ye3; Ma, Tiantai3; Hao JC(郝京诚)1 |
刊名 | Chemistry - A European Journal |
出版日期 | 2017 |
卷号 | 23期号:30页码:7278-7286 |
ISSN号 | 0947-6539 |
关键词 | honeycomb structure ionic liquid phase transfer photoluminescence polyoxometalates |
通讯作者 | 李洪光 ; 郝京诚 |
英文摘要 | Honeycomb-structured films represent an intriguing class of two-dimensional porous materials. Specifically, polyoxometalate (POM) macroanions can be introduced into these films by complexing with oppositely charged, doubletailed surfactants. Here highly-ordered honeycomb structures are reported that can be constructed by the complexes between POMs and a room temperature ionic liquid (IL1) having an imidazolium moiety in the middle and a naphthyl unit and a branched aliphatic chain at the ends. The complexes can be produced through phase transfer between an aqueous solution of POMs (typically {Mo72Fe30}) and a CS2 (or chloroform) solution of IL1. Based on the intrinsic properties of {Mo72Fe30} and the functional groups of the IL1, the honeycomb structures show multiple functions with bright photoluminescence and rich electrochemical properties. This work shows that by simply engineering the organic ligands involved in the POM-based inorganic-organic complexes, supramolecular structures with improved properties and wide applications can be obtained. |
学科主题 | 材料科学与物理化学 |
资助信息 | the National Natural Science Foundation of China (Nos. 21420102006;61474124);the Hundred Talents Program of Chinese Academy of Sciences (Y20245YBR1) |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000402640600020 |
源URL | [http://210.77.64.217/handle/362003/21970] |
专题 | 兰州化学物理研究所_清洁能源化学与材料实验室 兰州化学物理研究所_固体润滑国家重点实验室 |
作者单位 | 1.Key Laboratory of Colloid and Interface Chemistry & Key Laboratory of Special Aggregated Materials Ministry of Education, Shandong University Jinan, 250100 (P.R.China) 2.State Key Laboratory of Solid Lubrication Laboratory of Clean Energy Chemistry and Materials Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou, 730000 (P.R.China) 3.Taishan College, Shandong University Jinan, 250100 (P.R.China) |
推荐引用方式 GB/T 7714 | Zhang, Geping,Zhu, Hongxia,Chen, Mengjun,et al. Photoluminescent Honeycomb Structures from Polyoxometalates and an Imidazolium-Based Ionic Liquid Bearing a pi-Conjugated Moiety and a Branched Aliphatic Chain[J]. Chemistry - A European Journal,2017,23(30):7278-7286. |
APA | Zhang, Geping.,Zhu, Hongxia.,Chen, Mengjun.,Li HG.,Yuan, Ye.,...&Hao JC.(2017).Photoluminescent Honeycomb Structures from Polyoxometalates and an Imidazolium-Based Ionic Liquid Bearing a pi-Conjugated Moiety and a Branched Aliphatic Chain.Chemistry - A European Journal,23(30),7278-7286. |
MLA | Zhang, Geping,et al."Photoluminescent Honeycomb Structures from Polyoxometalates and an Imidazolium-Based Ionic Liquid Bearing a pi-Conjugated Moiety and a Branched Aliphatic Chain".Chemistry - A European Journal 23.30(2017):7278-7286. |
入库方式: OAI收割
来源:兰州化学物理研究所
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