Reactive compatibilization of LLDPE/PS blends with a new type of Lewis acid as catalyst
文献类型：期刊论文
| 作者 | Liu YL ; Shi Q ; Ke Z ; Yin LG ; Yin JH |
| 刊名 | polymer bulletin
 |
| 出版日期 | 2009 |
| 卷号 | 63期号:3页码:411–421 |
| 关键词 | IN-SITU COMPATIBILIZATION FRIEDEL-CRAFTS ALKYLATION MECHANICAL-PROPERTIES GRAFTING REACTION MORPHOLOGY POLYETHYLENE ENHANCEMENT COPOLYMER |
| ISSN号 | 0170-0839 |
| 通讯作者 | yin jh |
| 中文摘要 | the reactive compatibilization of lldpe/ps (50/50 wt%) was achieved by friedel-crafts alkylation reaction with a combined lewis acids (me3sicl and incl3 center dot 4h(2)o) as catalyst. the graft copolymer at the interface was characterized by fourier transform infrared spectroscopy and the morphology of the blends was analysized by scanning electron microscopy. it was found that the combined lewis acids had catalytic effect on friedel-crafts alkylation reaction between lldpe and ps, and the catalytic effect was maximal when the molar ratio of incl3 center dot 4h(2)o to me3sicl was 1:5. the graft copolymer lldpe-g-ps was formed via the f-c reaction and worked as a tailor-made compatibilizer to reduce the interfacial tension. the mechanical properties of reactive blend with combined lewis acids as catalyst was notably improved compared to that of physical lldpe/ps blend and serious degradation had been decreased compared to the reactive blend system with alcl3 as catalyst; we interpreted the above results in term of acidity of combined lewis acids. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000268328500008 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/12123]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu YL,Shi Q,Ke Z,et al. Reactive compatibilization of LLDPE/PS blends with a new type of Lewis acid as catalyst[J]. polymer bulletin,2009,63(3):411–421. |
| APA | Liu YL,Shi Q,Ke Z,Yin LG,&Yin JH.(2009).Reactive compatibilization of LLDPE/PS blends with a new type of Lewis acid as catalyst.polymer bulletin,63(3),411–421. |
| MLA | Liu YL,et al."Reactive compatibilization of LLDPE/PS blends with a new type of Lewis acid as catalyst".polymer bulletin 63.3(2009):411–421. |
入库方式： OAI收割
来源：长春应用化学研究所
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