Hydrothermal synthesis, crystal structure and electrochemical properties of a novel 3D Dawson-type polyoxometalate supramolecular network
文献类型：期刊论文
| 作者 | Tian LH ; Liu SZ ; Hu NH ; Jia HQ |
| 刊名 | journal of chemical research-s
 |
| 出版日期 | 2008 |
| 期号 | 11页码:626-629 |
| 关键词 | WELLS-DAWSON KEGGIN STRUCTURE COMPLEX OXIDATION CLUSTERS POLYMER |
| ISSN号 | 0308-2342 |
| 通讯作者 | liu sz |
| 中文摘要 | a novel dawson-type polyoxometalate supramolecular architecture of the formula [4,4'-h(2)bipy](2.5)center dot[4,4'-hbipy]center dot[p2w18o62]center dot 6.25h(2)o (4,4'-bipy = 4,4'-bipyridine) has been hydrothermally synthesised and characterised by means of elemental analysis, ir, cv and x-ray single-crystal diffraction. x-ray crystallography indicates that the title compound consists of dawson-type polyoxoaions [p2w18o62](6-), water molecules and 4,4'-bipy units. the polyoxoanion clusters together with 4,4'-bipy units and water molecules to construct the three-dimensional supramolecular network through hydrogen bonds. the crystal structure analyses reveal that water molecules and 4,4'-bipy units play the important role on the packing arrangements of crystals. cyclic voltammetry shows that the title compound exhibits three chemically reversible steps |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000261732700006 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/12177]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tian LH,Liu SZ,Hu NH,et al. Hydrothermal synthesis, crystal structure and electrochemical properties of a novel 3D Dawson-type polyoxometalate supramolecular network[J]. journal of chemical research-s,2008(11):626-629. |
| APA | Tian LH,Liu SZ,Hu NH,&Jia HQ.(2008).Hydrothermal synthesis, crystal structure and electrochemical properties of a novel 3D Dawson-type polyoxometalate supramolecular network.journal of chemical research-s(11),626-629. |
| MLA | Tian LH,et al."Hydrothermal synthesis, crystal structure and electrochemical properties of a novel 3D Dawson-type polyoxometalate supramolecular network".journal of chemical research-s .11(2008):626-629. |
入库方式： OAI收割
来源：长春应用化学研究所
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