中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Successful establishment of MEKC with electrochemiluminescence detection based on one functionalized ionic liquid

文献类型:期刊论文

作者Xu YH ; Fang LY ; Wang EK
刊名electrophoresis
出版日期2009
卷号30期号:2页码:365-371
关键词MICELLAR ELECTROKINETIC CHROMATOGRAPHY CAPILLARY-ZONE-ELECTROPHORESIS ELECTROGENERATED CHEMILUMINESCENCE BACKGROUND ELECTROLYTE SEPARATION ACID HYDROXYPROLINE FLUORESCENCE PYRENE DRUGS
ISSN号0173-0835
通讯作者wang ek
中文摘要herein, one water-soluble functionalized ionic liquid, 1-butyl-3-methylimidazolium dodecyl sulfate ([bmim(+)][c12h25so4-]), was designed and its superiorities either used as supporting electrolytes or as additives for successful establishment of mekc with electrochemiluminescence (ecl) detection (mekc-ecl) method were investigated. compared with the common supporting electrolytes such as phosphate solution, 1-butyl-3-methylimidazolium dodecyl sulfate solution used as running buffers led to greatly enhanced ecl intensities and column efficiencies for negative targets, a little increase for neutral-charge ones while maintained nearly unchanged for positive ones due to the electrostatic forces between the large cation bmim(+) and the solutes and the hydrophobic interactions resulting from the large anion c12h25so4.
收录类别SCI
语种英语
WOS记录号WOS:000263708900009
公开日期2010-05-27
源URL[http://202.98.16.49/handle/322003/12219]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Xu YH,Fang LY,Wang EK. Successful establishment of MEKC with electrochemiluminescence detection based on one functionalized ionic liquid[J]. electrophoresis,2009,30(2):365-371.
APA Xu YH,Fang LY,&Wang EK.(2009).Successful establishment of MEKC with electrochemiluminescence detection based on one functionalized ionic liquid.electrophoresis,30(2),365-371.
MLA Xu YH,et al."Successful establishment of MEKC with electrochemiluminescence detection based on one functionalized ionic liquid".electrophoresis 30.2(2009):365-371.

入库方式: OAI收割

来源:长春应用化学研究所

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