Polyethylene glycol-stabilized platinum nanoparticles: The efficient and recyclable catalysts for selective hydrogenation of o-chloronitrobenzene to o-chloroaniline
文献类型:期刊论文
作者 | Cheng HY ; Xi CY ; Meng XC ; Hao YF ; Yu YC ; Zhao FY |
刊名 | journal of colloid and interface science
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出版日期 | 2009 |
卷号 | 336期号:2页码:675-678 |
关键词 | PALLADIUM NANOPARTICLES HECK REACTION METAL CLUSTERS COLLOIDS NANOCATALYSTS PARTICLES IONS |
ISSN号 | 0021-9797 |
通讯作者 | zhao fy |
中文摘要 | in the present work, platinum nanoparticles were prepared by in situ reduction with polyethylene glycols (pegs). the catalytic performance of pt nanoparticles immobilized in pegs (pt-pegs) is discussed for the hydrogenation of o-chloronitrobenzene (o-cnb). a high selectivity to o-chloroaniline (o-can) of about 99.7% was obtained with the pt-pegs catalysts at the complete conversion of o-cnb, which is much higher than that (83.4%) obtained over the conventional catalyst of pt/c. the pt nanoparticies could be immobilized in pegs stably and recycled for four times with the same activity and selectivity. it presents a promising performance in the hydrogenation and its wide application in catalytic reactions is expected. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000267671400040 |
公开日期 | 2010-05-27 |
源URL | [http://ir.ciac.jl.cn/handle/322003/12229] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Cheng HY,Xi CY,Meng XC,et al. Polyethylene glycol-stabilized platinum nanoparticles: The efficient and recyclable catalysts for selective hydrogenation of o-chloronitrobenzene to o-chloroaniline[J]. journal of colloid and interface science,2009,336(2):675-678. |
APA | Cheng HY,Xi CY,Meng XC,Hao YF,Yu YC,&Zhao FY.(2009).Polyethylene glycol-stabilized platinum nanoparticles: The efficient and recyclable catalysts for selective hydrogenation of o-chloronitrobenzene to o-chloroaniline.journal of colloid and interface science,336(2),675-678. |
MLA | Cheng HY,et al."Polyethylene glycol-stabilized platinum nanoparticles: The efficient and recyclable catalysts for selective hydrogenation of o-chloronitrobenzene to o-chloroaniline".journal of colloid and interface science 336.2(2009):675-678. |
入库方式: OAI收割
来源:长春应用化学研究所
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