Influence of metal particle size on the hydrogenation of maleic anhydride over Pd/C catalysts in scCO(2)
文献类型：期刊论文
| 作者 | Wang Q ; Cheng HY ; Liu RX ; Hao JM ; Yu YC ; Zhao FY |
| 刊名 | catalysis today
 |
| 出版日期 | 2009 |
| 卷号 | 148期号:3-4页码:368-372 |
| 关键词 | SUPERCRITICAL CARBON-DIOXIDE SELECTIVE HYDROGENATION ASYMMETRIC HYDROGENATION HETEROGENEOUS CATALYSIS MOLECULAR-INTERACTIONS GAMMA-BUTYROLACTONE PD/AL2O3 CATALYST CO2 MEDIUM FLUIDS NITROBENZENE |
| ISSN号 | 0920-5861 |
| 通讯作者 | zhao fy |
| 中文摘要 | hydrogenation of maleic anhydride (mah) with pd/c catalysts in supercritical carbon dioxide (scco(2)) was investigated. the selectivity for gamma-butyrolactone (gbl) reached 97.3% in scco(2) at 100% conversion of mah, which was notably higher than that of 77.4% obtained in organic solvent of ethylene glycol dimethyl ether (egdme). the particle size of pd exhibited large influence on the reaction rate and selectivity of gbl. higher selectivity of gbl was obtained with pd/c catalyst of smaller pd particle size, and the rate of gbl selectivity increase as a function of co2 pressure was found to be significantly correlated with pd particle size. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000272972400026 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/12247]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wang Q,Cheng HY,Liu RX,et al. Influence of metal particle size on the hydrogenation of maleic anhydride over Pd/C catalysts in scCO(2)[J]. catalysis today,2009,148(3-4):368-372. |
| APA | Wang Q,Cheng HY,Liu RX,Hao JM,Yu YC,&Zhao FY.(2009).Influence of metal particle size on the hydrogenation of maleic anhydride over Pd/C catalysts in scCO(2).catalysis today,148(3-4),368-372. |
| MLA | Wang Q,et al."Influence of metal particle size on the hydrogenation of maleic anhydride over Pd/C catalysts in scCO(2)".catalysis today 148.3-4(2009):368-372. |
入库方式： OAI收割
来源：长春应用化学研究所
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