Reactivity of Rare-Earth Metal Complexes Stabilized by an Anilido-Phosphinimine Ligand
文献类型：期刊论文
| 作者 | Liu B ; Liu XL ; Cui DM ; Liu L |
| 刊名 | organometallics
 |
| 出版日期 | 2009 |
| 卷号 | 28期号:5页码:1453-1460 |
| 关键词 | LANTHANIDE ALKYL COMPLEXES BETA-DIKETIMINATO LIGANDS OLEFIN-POLYMERIZATION CATALYTIC-ACTIVITY METHYL COMPLEXES ETHYLENE POLYMERIZATION CYCLOPENTADIENYL LIGAND ISOPRENE POLYMERIZATION LIVING POLYMERIZATION MOLECULAR-STRUCTURE |
| ISSN号 | 0276-7333 |
| 通讯作者 | cui dm |
| 中文摘要 | treatment of anilido-phosphinimine-ligated yttrium mono(alkyl) complex 1a, ly(ch2si(ch3)(3))(thf) (l = o-(2,6-(c6h3pr2)-pr-i)nc6h4p(c6h4)(c6h5)n(2,4,6-c6h2me3)), with 2 equiv of phenylsilane in dme afforded methoxy-bridged complex 2, [ly(mu-och3)](2), via the corresponding hydrido intermediate. when excess isoprene was added to the mixture of la and phenylsilane, a eta(3)-isopentene product, 3, ly(ch2c(ch3)=chch3)(thf), was isolated. a lutetium chloride, llucl(dme) (4), was generated through the reaction of lutetium mono(alkyl) complex 1b, llu(ch2si(ch3)(3))(thf), with [ph3c]-[b(c6f5)(4)]center dot licl accompanied by the formation of [li(dme)(3)](+)[b(c6f5)(4)](-). metathesis reaction of 1b with excess alme3 at room temperature gave a methyl-terminated counterpart, 5, llu(ch3)(thf)(2). in all these reactions, the ln-c-phenyl bonds of complexes 1 remained untouched. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000263800700023 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/12357]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu B,Liu XL,Cui DM,et al. Reactivity of Rare-Earth Metal Complexes Stabilized by an Anilido-Phosphinimine Ligand[J]. organometallics,2009,28(5):1453-1460. |
| APA | Liu B,Liu XL,Cui DM,&Liu L.(2009).Reactivity of Rare-Earth Metal Complexes Stabilized by an Anilido-Phosphinimine Ligand.organometallics,28(5),1453-1460. |
| MLA | Liu B,et al."Reactivity of Rare-Earth Metal Complexes Stabilized by an Anilido-Phosphinimine Ligand".organometallics 28.5(2009):1453-1460. |
入库方式： OAI收割
来源：长春应用化学研究所
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