Conducting polyaniline film from aqueous dispersion: Crystallizable side chain forced lamellar structure for high conductivity
文献类型：期刊论文
| 作者 | Zhang HM ; Wang XH ; Li J ; Mo ZS ; Wang FS |
| 刊名 | polymer
 |
| 出版日期 | 2009 |
| 卷号 | 50期号:12页码:2674-2679 |
| ISSN号 | 0032-3861 |
| 关键词 | WATER-SOLUBLE POLYANILINE X-RAY ELECTRICAL-CONDUCTIVITY SULFONATED POLYANILINE POLYMER ACID PROCESSIBILITY SOLVENTS DIFFRACTION COSOLVENTS |
| 通讯作者 | wang xh |
| 中文摘要 | aqueous conducting polyaniline dispersion was prepared employing acidic phosphate ester bearing hydrophilic ethylene glycol segment as dopant, and conducting film with electrical conductivity of 25 s/cm was obtained from the dispersion. ordered self-assembly lamellar structure with interlamellar distance of 1.2 nm was observed in the film, which consisted of alternating layers of rigid polyaniline chain and flexible phosphate ester side chains, where the phosphate side chain layer was separated by two rigid polyaniline layers. the lamellar structure leading to high conducting film was formed due to the confinement of polyaniline chain by crystallizable phosphate side chain, since the electrical conductivity decreased by four orders of magnitude once the dopant side chain crystalline was destroyed. the crystallizable side chain forced lamellar structure is expected to be a new chance for highly conducting polyaniline. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000266706800020 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/12399]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang HM,Wang XH,Li J,et al. Conducting polyaniline film from aqueous dispersion: Crystallizable side chain forced lamellar structure for high conductivity[J]. polymer,2009,50(12):2674-2679. |
| APA | Zhang HM,Wang XH,Li J,Mo ZS,&Wang FS.(2009).Conducting polyaniline film from aqueous dispersion: Crystallizable side chain forced lamellar structure for high conductivity.polymer,50(12),2674-2679. |
| MLA | Zhang HM,et al."Conducting polyaniline film from aqueous dispersion: Crystallizable side chain forced lamellar structure for high conductivity".polymer 50.12(2009):2674-2679. |
入库方式： OAI收割
来源：长春应用化学研究所
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