Facile, Efficient Copolymerization of Ethylene with Bicyclic, Non-Conjugated Dienes by Titanium Complexes Bearing Bis(beta-Enaminoketonato) Ligands
文献类型：期刊论文
| 作者 | Liu JY ; Liu SR ; Pan L ; Li YS |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2009 |
| 卷号 | 351期号:10页码:1505-1511 |
| 关键词 | REGIOSELECTIVE COPOLYMERIZATION ENANTIOSELECTIVE CYCLOPOLYMERIZATION METALLOCENE METHYLALUMINOXANE ZIRCONOCENE-METHYLALUMINOXANE OLEFIN POLYMERIZATION CATALYST SYSTEM MAIN-CHAIN 5-VINYL-2-NORBORNENE 1 HOMOPOLYMERIZATION 5-HEXADIENE |
| ISSN号 | 1615-4150 |
| 通讯作者 | li ys |
| 中文摘要 | copolymerizations of ethylene with 5-vinyl-2-norbornene or 5-ethylidene-2-norbornene under the action of various titanium complexes bearing bis(beta-enaminoketonato) chelate ligands of the type, [(rn)-n-1=c(r-2)ch=c(r-3)o](2)ticl2 (1, r-1=ph, r-2=cf3, r-3=ph; 2, r-1=c6h4f-p, r-2=cf3, r-3=ph; 3, r-1=ph, r-2=cf3, r-3=t-bu; 4, r-1=c6h4f-p, r-2=cf3, r-3=t-bu; 5, r-1=ph, r-2=ch3, r-3=cf3; 6, r-1=c6h4f-p, r-2=ch3 r-3=cf3), have been shown to occur with the regioselective insertion of the endocyclic double bond of the monomer into the copolymer chain, leaving the exocyclic vinyl double bond as a pendant unsaturation. the ligand modification strongly affects the copolymerization behaviour. high catalytic activities and efficient co-monomer incorporation can be easily obtained by optimizing the catalyst structures and polymerization conditions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000268200500007 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/12449]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu JY,Liu SR,Pan L,et al. Facile, Efficient Copolymerization of Ethylene with Bicyclic, Non-Conjugated Dienes by Titanium Complexes Bearing Bis(beta-Enaminoketonato) Ligands[J]. advanced synthesis & catalysis,2009,351(10):1505-1511. |
| APA | Liu JY,Liu SR,Pan L,&Li YS.(2009).Facile, Efficient Copolymerization of Ethylene with Bicyclic, Non-Conjugated Dienes by Titanium Complexes Bearing Bis(beta-Enaminoketonato) Ligands.advanced synthesis & catalysis,351(10),1505-1511. |
| MLA | Liu JY,et al."Facile, Efficient Copolymerization of Ethylene with Bicyclic, Non-Conjugated Dienes by Titanium Complexes Bearing Bis(beta-Enaminoketonato) Ligands".advanced synthesis & catalysis 351.10(2009):1505-1511. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。