Synthesis and Characterization of Hyperbranched Poly(ether amide)s with Thermoresponsive Property and Unexpected Strong Blue Photoluminescence
文献类型：期刊论文
| 作者 | Lin Y ; Gao JW ; Liu HW ; Li YS |
| 刊名 | macromolecules
 |
| 出版日期 | 2009 |
| 卷号 | 42期号:9页码:3237-3246 |
| 关键词 | CONDENSING VINYL POLYMERIZATION PROTON-TRANSFER POLYMERIZATION AVAILABLE DICARBOXYLIC-ACIDS TRANSFER RAFT POLYMERIZATION STIMULI-RESPONSIVE POLYMERS MICHAEL-TYPE ADDITION BB'(2) TYPE MONOMERS ONE-POT SYNTHESIS RADICAL POLYMERIZATION POLY(AMIDOAMINE) DENDRIMERS |
| ISSN号 | 0024-9297 |
| 通讯作者 | li ys |
| 中文摘要 | a facile and efficient strategy for the syntheses of novel hyperbranched poly(ether amide)s (hpea) from multihydroxyl primary amines and (meth)acryloyl chloride has been developed. the chemical structures of the hpeas were confirmed by ir and nmr spectra. analyses of sec (size exclusion chromatography) and viscosity characterizations revealed the highly branched structures of the polymers obtained. the resultant hyperbranched polymers contain abundant hydroxyl groups. the thermoresponsive property was obtained from in situ surface modification of abundant oh end groups with n-isopropylacrylamide (nipaam). the study oil temperature-dependent characteristics has revealed that nipaam-g-hpea exhibits an adjustable lower critical solution temperature (lcst) of about 34-42 degrees c depending on the grafting degree. more interestingly, the work provided an interesting phenomenon where the hpea backbones exhibited strong blue photoluminescence. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000265781300005 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/12451]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Lin Y,Gao JW,Liu HW,et al. Synthesis and Characterization of Hyperbranched Poly(ether amide)s with Thermoresponsive Property and Unexpected Strong Blue Photoluminescence[J]. macromolecules,2009,42(9):3237-3246. |
| APA | Lin Y,Gao JW,Liu HW,&Li YS.(2009).Synthesis and Characterization of Hyperbranched Poly(ether amide)s with Thermoresponsive Property and Unexpected Strong Blue Photoluminescence.macromolecules,42(9),3237-3246. |
| MLA | Lin Y,et al."Synthesis and Characterization of Hyperbranched Poly(ether amide)s with Thermoresponsive Property and Unexpected Strong Blue Photoluminescence".macromolecules 42.9(2009):3237-3246. |
入库方式： OAI收割
来源：长春应用化学研究所
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