Ethylene Polymerization and Ethylene/Hexene Copolymerization with Vanadium(III) Catalysts Bearing Heteroatom-Containing Salicylaldiminato Ligands
文献类型：期刊论文
| 作者 | Wu JQ ; Pan L ; Liu SR ; He LP ; Li YS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2009 |
| 卷号 | 47期号:14页码:3573-3582 |
| 关键词 | POLYETHYLENE CHAIN GROWTH OPENING METATHESIS POLYMERIZATION LIVING COORDINATION POLYMERIZATION MOLECULAR-WEIGHT DISTRIBUTION TRANSITION-METAL-COMPLEXES ZIEGLER-NATTA CATALYSTS OLEFIN POLYMERIZATION STRUCTURAL-CHARACTERIZATION SINGLE-SITE O N-CHELATING AMINOPHENOLATE |
| ISSN号 | 0887-624x |
| 通讯作者 | li ys |
| 中文摘要 | a series of novel vanadium(iii) complexes hearing heteroatoill-containing group-substituted salicylaldiminato ligands [rn=ch(aro)]vcl2(thf)(2) (ar = c6h4, r = c3h2ns, 2a; c7h4ns, 2c; c7h5n2, 2d; ar = c(6)h(2)tbu(2) (2,4), r = c3h2ns, 2b) have been synthesized and characterized. structure of complex 2c was further confirmed by x-ray crystallographic analysis. the complexes were investigated as the catalysts for ethylene polymerization in the presence of et2alcl. complexes 2a-d exhibited high catalytic activities (up to 22.8 kg polyethylene/mmolv h bar), and affording polymer with unimodal molecular weight distributions at 25-70 degrees c in the first 5-min polymerization, whereas produced bimodal molecular weight distribution polymers at 70 degrees c when polymerization time prolonged to 30 min. the catalyst structure plays an important role in controlling the molecular weight and molecular weight distribution of the resultant polymers produced in 30 min polymerization. in addition, ethylene/hexene copolymerizations with catalysts 2a-d were also explored in the presence of et2alcl, which leads to the high molecular weight and unimodal distributions copolymers with high comonomer incorporation. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000267444200009 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/12471]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu JQ,Pan L,Liu SR,et al. Ethylene Polymerization and Ethylene/Hexene Copolymerization with Vanadium(III) Catalysts Bearing Heteroatom-Containing Salicylaldiminato Ligands[J]. journal of polymer science part a-polymer chemistry,2009,47(14):3573-3582. |
| APA | Wu JQ,Pan L,Liu SR,He LP,&Li YS.(2009).Ethylene Polymerization and Ethylene/Hexene Copolymerization with Vanadium(III) Catalysts Bearing Heteroatom-Containing Salicylaldiminato Ligands.journal of polymer science part a-polymer chemistry,47(14),3573-3582. |
| MLA | Wu JQ,et al."Ethylene Polymerization and Ethylene/Hexene Copolymerization with Vanadium(III) Catalysts Bearing Heteroatom-Containing Salicylaldiminato Ligands".journal of polymer science part a-polymer chemistry 47.14(2009):3573-3582. |
入库方式： OAI收割
来源：长春应用化学研究所
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