Free-Radical Solution Copolymerization of the Ionic Liquid Monomer 1-Vinyl-3-Ethylimidazolium Bromide with Acrylonitrile
文献类型：期刊论文
| 作者 | Zhang GB ; Liu XH ; Li BX ; Bai YG |
| 刊名 | journal of applied polymer science
 |
| 出版日期 | 2009 |
| 卷号 | 112期号:6页码:3337-3340 |
| 关键词 | APPARENT REACTIVITY RATIOS METHYL VINYL KETONE MOLTEN-SALTS POLYMERIZATION PRECURSOR ACRYLATE SYSTEM |
| ISSN号 | 0021-8995 |
| 通讯作者 | zhang gb |
| 中文摘要 | ionic liquid monomer 1-vinyl-3-ethylimidazolium bromide (vietim(+)br(-)) was first used to copolymerize with acrylonitrile (an) successfully under various conditions. this was achieved with azobisisobutyronitrile as the initiator and dimethyl sulfoxide as the solvent. the kinetics of this copolymerization were studied. the values of the monomer apparent reactivity ratios were calculated by the kelen-tudos method. the apparent reactivity ratios of vietim(+)br(-) (r(vietim+br-)) and an (r(an)) were similar at polymerization conversions of less than 10%, (r(an) = 0.954, r(vietim+br-) = 0.976). the copolymers were obtained with high molecular weights and high hydrophilicides. the copolymers were characterized by h-1-nmr, differential scanning calorimetry, and thermogravimetric analysis. these copolymers may be potentially useful in the preparation of precursor fibers and carbon fibers. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000265422100021 |
| 公开日期 | 2010-05-27 |
| 源URL | [http://202.98.16.49/handle/322003/12489]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang GB,Liu XH,Li BX,et al. Free-Radical Solution Copolymerization of the Ionic Liquid Monomer 1-Vinyl-3-Ethylimidazolium Bromide with Acrylonitrile[J]. journal of applied polymer science,2009,112(6):3337-3340. |
| APA | Zhang GB,Liu XH,Li BX,&Bai YG.(2009).Free-Radical Solution Copolymerization of the Ionic Liquid Monomer 1-Vinyl-3-Ethylimidazolium Bromide with Acrylonitrile.journal of applied polymer science,112(6),3337-3340. |
| MLA | Zhang GB,et al."Free-Radical Solution Copolymerization of the Ionic Liquid Monomer 1-Vinyl-3-Ethylimidazolium Bromide with Acrylonitrile".journal of applied polymer science 112.6(2009):3337-3340. |
入库方式： OAI收割
来源：长春应用化学研究所
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