Quantum dot electrochemiluminescence in aqueous solution at lower potential and its sensing application
文献类型：期刊论文
| 作者 | Zhang LH ; Zou XQ ; Ying E ; Dong SJ |
| 刊名 | journal of physical chemistry c
 |
| 出版日期 | 2008 |
| 卷号 | 112期号:12页码:4451-4454 |
| 关键词 | LIGHT-EMITTING-DIODES ELECTROGENERATED CHEMILUMINESCENCE SEMICONDUCTOR NANOCRYSTALS POLYMER CDSE ELECTROCHEMISTRY CDTE ELECTROLUMINESCENCE SYSTEM |
| ISSN号 | 1932-7447 |
| 通讯作者 | dong sj |
| 中文摘要 | the unique strategy for electrochemiluminescence (ecl) sensor based on the quantum dots (qds) oxidation in aqueous solution to detect amines is proposed for the first time. actually, there existed two qds ecl peaks in anhydrous solution, one at high positive potential and another at high negative potential. however, here we introduced the qds oxidation ecl in aqueous solution to fabricate a novel ecl sensor. such sensor needed only lower positive potential to produce ecl, which could prevent the interferences resulted from high potential as that of qds reduction ecl in aqueous solution. therefore, the present work not only extended the qds oxidation ecl application field from anhydrous to aqueous solution but also enriched the variety of ecl system in aqueous solution. furthermore, we investigated the qds oxidation ecl toward different kinds of amines, and found that both aliphatic alkyl and hydroxy groups could lead to the enhancement of ecl intensity. among these amines, 2-(dibutylamino)ethanol (dbae) is the most effective one, and accordingly, the first ecl sensing application of the qds oxidation ecl toward dbae is developed; the as-prepared ecl sensor shows wide linear range, high sensitivity, and good stability. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000255108700005 |
| 公开日期 | 2010-06-18 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/12589]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang LH,Zou XQ,Ying E,et al. Quantum dot electrochemiluminescence in aqueous solution at lower potential and its sensing application[J]. journal of physical chemistry c,2008,112(12):4451-4454. |
| APA | Zhang LH,Zou XQ,Ying E,&Dong SJ.(2008).Quantum dot electrochemiluminescence in aqueous solution at lower potential and its sensing application.journal of physical chemistry c,112(12),4451-4454. |
| MLA | Zhang LH,et al."Quantum dot electrochemiluminescence in aqueous solution at lower potential and its sensing application".journal of physical chemistry c 112.12(2008):4451-4454. |
入库方式： OAI收割
来源：长春应用化学研究所
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