Layered Double Hydroxides Derived ZnO-Al2O3 Supported Pd-Ag Catalysts for Selective Hydrogenation of Acetylene
文献类型：期刊论文
| 作者 | Gao, Xiaoping ; Zhou, Yanan ; Jing, Fangli ; Luo, Jingjie ; Huang, Qingsong ; Chu, Wei |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2017-06-01 |
| 卷号 | 35期号:6页码:1009-1015 |
| 关键词 | ZnAl-LDH Pd catalyst Ag promoter acetylene selective hydrogenation high selectivity |
| ISSN号 | 1001-604X |
| 通讯作者 | Jing, FL (reprint author), Sichuan Univ, Sch Chem Engn, Chengdu 610065, Sichuan, Peoples R China. ; Jing, FL (reprint author), Sichuan Univ, Inst New Energy & Low Carbon Technol, Chengdu 610207, Sichuan, Peoples R China. |
| 中文摘要 | ZnO-Al2O3 derived from layered double hydroxides (ZnAl-LDH) was successfully applied for dispersion of Pd-Ag bimetallic catalysts for the selective hydrogenation of acetylene to ethylene and the Pd-Ag/ZnO-Al2O3 catalyst showed the best catalytic performance among the prepared samples. It was found that the catalyst carrier of ZnO-Al2O3 metal-oxides derived form ZnAl-LDH could significantly suppress the over-hydrogenation of acetylene to obtain the relatively higher selectivity of ethylene. The introduction of Ag restricted efficiently the formation of coke because of the oligomerization reaction, which was further evidenced by thermal gravimetric analysis. The selectivity towards ethylene was in the order of Pd-Ag/ZnO-Al2O3>Pd/ZnO-Al2O3>Pd-Ag/Al2O3>Pd/Al2O3 at a high conversion level. As the thermal gravimetric and differential temperature analysis (TG-DTA) revealed, Pd-Ag intermetallic catalyst on the ZnO-Al2O3 support showed less coke formation. |
| 学科主题 | Chemistry, Multidisciplinary |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China [21476145]; China Cheng Da Engineering Co., Ltd |
| 语种 | 英语 |
| 公开日期 | 2017-08-17 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/78101]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Gao, Xiaoping,Zhou, Yanan,Jing, Fangli,et al. Layered Double Hydroxides Derived ZnO-Al2O3 Supported Pd-Ag Catalysts for Selective Hydrogenation of Acetylene[J]. CHINESE JOURNAL OF CHEMISTRY,2017,35(6):1009-1015. |
| APA | Gao, Xiaoping,Zhou, Yanan,Jing, Fangli,Luo, Jingjie,Huang, Qingsong,&Chu, Wei.(2017).Layered Double Hydroxides Derived ZnO-Al2O3 Supported Pd-Ag Catalysts for Selective Hydrogenation of Acetylene.CHINESE JOURNAL OF CHEMISTRY,35(6),1009-1015. |
| MLA | Gao, Xiaoping,et al."Layered Double Hydroxides Derived ZnO-Al2O3 Supported Pd-Ag Catalysts for Selective Hydrogenation of Acetylene".CHINESE JOURNAL OF CHEMISTRY 35.6(2017):1009-1015. |
入库方式： OAI收割
来源：金属研究所
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