Ruthenium-nickel-nickel hydroxide nanoparticles for room temperature catalytic hydrogenation
文献类型：期刊论文
| 作者 | Zhu, Lihua ; Shan, Shiyao ; Petkov, Valeri ; Hu, Weiwei ; Kroner, Anna ; Zheng, Jinbao ; Yu, Changlin ; Zhang, Nuowei ; Li, Yunhua ; Luque, Rafael ; Zhong, Chuan-Jian ; Ye, Hengqiang ; Yang, Zhiqing ; Chen, Bing H. |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2017-05-07 |
| 卷号 | 5期号:17页码:7869-7875 |
| ISSN号 | 2050-7488 |
| 通讯作者 | Zhu, LH (reprint author), Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China. ; Zhu, LH ; Luque, R ; Chen, BH (reprint author), Xiamen Univ, Coll Chem & Chem Engn, Natl Engn Lab Green Prod Alcohols Ethers Ester, Dept Chem & Biochem Engn, Xiamen 361005, Peoples R China. ; Yang, ZQ (reprint author), Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China. ; Luque, R (reprint author), Univ Cordoba, Dept Quim Organ, Campus Rabanales,Edificio Marie Curie C-3, E-14071 Cordoba, Spain. |
| 中文摘要 | Improving the utilization of metals in heterogeneous catalysts with excellent catalytic performance, high selectivity and good stability represents a major challenge. Herein a new strategy is disclosed by enabling a nanoscale synergy between a transition metal and a noble metal. A novel Ru/Ni/Ni(OH)(2)/C catalyst, which is a hybrid of Ru nanoclusters anchored on Ni/Ni(OH)(2) nanoparticles (NPs), was designed, prepared and characterized. The Ru/Ni/Ni(OH)(2)/C catalyst exhibited a remarkable catalytic activity for naphthalene hydrogenation in comparison with existing Ru/C, Ni/Ni(OH)(2)/C and Ru-Ni alloy/C catalysts. This is mainly attributed to the interfacial Ru, Ni and Ni(OH)(2) sites of Ru/Ni/Ni(OH)(2)/C, where hydrogen is adsorbed and activated on Ru while Ni transfers the activated hydrogen species (as a "bridge") to the activated naphthalene on Ni(OH)(2) sites, producing decalin through a highly effective pathway. |
| 学科主题 | Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 收录类别 | SCI |
| 资助信息 | Natural Science Foundation of Jiangxi Province of China [20161BAB213083]; Research Foundation of the Education Bureau of Jiangxi Province of China [GJJ160666]; National Natural Science Foundation of China [21303140, 21466013, 51371178, 51390473]; DOE-BES Grant [DE-SC0006877]; DOE [DEAC02-06CH11357] |
| 语种 | 英语 |
| 公开日期 | 2017-08-17 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/78143]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Zhu, Lihua,Shan, Shiyao,Petkov, Valeri,et al. Ruthenium-nickel-nickel hydroxide nanoparticles for room temperature catalytic hydrogenation[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(17):7869-7875. |
| APA | Zhu, Lihua.,Shan, Shiyao.,Petkov, Valeri.,Hu, Weiwei.,Kroner, Anna.,...&Chen, Bing H..(2017).Ruthenium-nickel-nickel hydroxide nanoparticles for room temperature catalytic hydrogenation.JOURNAL OF MATERIALS CHEMISTRY A,5(17),7869-7875. |
| MLA | Zhu, Lihua,et al."Ruthenium-nickel-nickel hydroxide nanoparticles for room temperature catalytic hydrogenation".JOURNAL OF MATERIALS CHEMISTRY A 5.17(2017):7869-7875. |
入库方式： OAI收割
来源：金属研究所
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