Is niobium more corrosion-resistant than commercially pure titanium in fluoride-containing artificial saliva?
文献类型：期刊论文
| 作者 | Li, Yu ; Xu, Jian |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2017-04-10 |
| 卷号 | 233页码:151-166 |
| 关键词 | Niobium Artificial saliva Fluoride Passivation Titanium |
| ISSN号 | 0013-4686 |
| 通讯作者 | Xu, J (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China. |
| 中文摘要 | In this work, commercially pure niobium (c. p. Nb) was selected to study its electrochemical behaviour in artificial saliva with several concentrations of fluoride ions (F ) over a range of 0-0.24M. The chemical nature of passive layers on surface was characterised with x-ray photoelectron spectroscopy (XPS). The changes in surface topography due to F -inducedcorrosion were examined with scanning electron microscopy (SEM). For comparison, commercially pure titanium (c. p. Ti) was also investigated under identical conditions. Both c. p. Nb and c. p. Ti exhibit very good corrosion resistance in artificial saliva without F or with a low level of F showing a low passive current density (j(pass)) andhigh polarisation resistance (Rp). However, as the F concentration increases, c. p. Nb demonstrates a significantly greater corrosion resistance due to its stable passive film (mainly Nb2O5) with a thickness of several nanometres, showing a much lower j(pass) and higher Rp, with both values differing from those of c. p. Ti by over one order of magnitude. Significant differences in the corrosion behaviour between c. p. Nb and c. p. Ti can be understood from the thermodynamic perspective and the propensity of oxide dissolution. The advantage of niobium over titanium merits attention, as the c. p. Nb and Nb-based alloys are promising for further applications in dental prosthesis fabrication. (C) 2017 Elsevier Ltd. All rights reserved. |
| 学科主题 | Electrochemistry |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China [51571192] |
| 语种 | 英语 |
| 公开日期 | 2017-08-17 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/78186]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Li, Yu,Xu, Jian. Is niobium more corrosion-resistant than commercially pure titanium in fluoride-containing artificial saliva?[J]. ELECTROCHIMICA ACTA,2017,233:151-166. |
| APA | Li, Yu,&Xu, Jian.(2017).Is niobium more corrosion-resistant than commercially pure titanium in fluoride-containing artificial saliva?.ELECTROCHIMICA ACTA,233,151-166. |
| MLA | Li, Yu,et al."Is niobium more corrosion-resistant than commercially pure titanium in fluoride-containing artificial saliva?".ELECTROCHIMICA ACTA 233(2017):151-166. |
入库方式： OAI收割
来源：金属研究所
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