Strain-induced ordered structure of titanium carbide during depositing diamond on Ti alloy substrate
文献类型:期刊论文
作者 | Li, X. J. ; He, L. L. ; Li, Y. S. ; Yang, Q. ; Hirose, A. |
刊名 | MATERIALS CHARACTERIZATION
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出版日期 | 2017 |
卷号 | 123页码:227-232 |
关键词 | HRTEM 6H-type TiC Carbon vacancies Interfacial stress Diamond film Ti alloy substrate |
ISSN号 | 1044-5803 |
中文摘要 | During the deposition of diamond films on Ti alloy substrates, titanium carbide is a common precipitated phase, preferentially formed at the interfacial region. However, in this case, the precipitation of an ordered structure of titanium carbide has not been reported. In our work, a long periodic ordered structure of TiC has been observed at the deposited diamond film/Ti alloy interface by high resolution transmission electron microscopy (HRTEM). The long periodic ordered structure is identified as 6H-type. The formation mechanism is revealed by comparative studies on the different structures of TiC precipitated under different diamond deposition conditions in terms of deposition time, atmosphere and temperature. A large number of carbon vacancies in the interfacial precipitated TiC phase are verified through electron energy loss spectroscopy (EELS) quantification analysis. However, an ordered arrangement of these carbon vacancies occurs only when the interfacial stress is large enough to induce the precipitation of 6H-type TiC. The supplementary analysis by X-ray diffraction (XRD) further confirms that additional diffraction peaks presented in the XRD patterns are corresponding to the precipitation of 6H-type TiC. (C) 2016 Elsevier Inc. All rights reserved. |
学科主题 | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering ; Materials Science, Characterization & Testing |
收录类别 | SCI |
资助信息 | Department of Education of Jilin Province [2016331]; National Basic Research Program of China [2011CB605803, 2011CB605604]; Canada Research Chair Program; Natural Sciences and Engineering Research Council of Canada (NSERC) |
语种 | 英语 |
公开日期 | 2017-08-17 |
源URL | [http://ir.imr.ac.cn/handle/321006/78376] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Li, X. J.,He, L. L.,Li, Y. S.,et al. Strain-induced ordered structure of titanium carbide during depositing diamond on Ti alloy substrate[J]. MATERIALS CHARACTERIZATION,2017,123:227-232. |
APA | Li, X. J.,He, L. L.,Li, Y. S.,Yang, Q.,&Hirose, A..(2017).Strain-induced ordered structure of titanium carbide during depositing diamond on Ti alloy substrate.MATERIALS CHARACTERIZATION,123,227-232. |
MLA | Li, X. J.,et al."Strain-induced ordered structure of titanium carbide during depositing diamond on Ti alloy substrate".MATERIALS CHARACTERIZATION 123(2017):227-232. |
入库方式: OAI收割
来源:金属研究所
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