Coproduction of Furfural and Easily Hydrolyzable Residue from Sugar Cane Bagasse in the MTHF/Aqueous Biphasic System: Influence of Acid Species, NaCl Addition, and MTHF
文献类型：期刊论文
| 作者 | Li, Xing-kang ; Fang, Zhen ; Luo, Jia ; Su, Tong-chao |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:10页码:5804-5813 |
| ISSN号 | 2168-0485 |
| 中文摘要 | In order to develop a process for the simultaneous production of furfural and easily hydrolyzable cellulose, the degradation of sugar cane bagasse in a single aqueous system and in a 2-methyltetrahydrofuran (MTHF)/aqueous AlCl3 biphasic system was studied. In single aqueous system, the influence of acid species (FeCl3, HC1, and AlCl3) on furfural production and cellulose degradation was investigated at 150 degrees C. FeCl3 and HC1 promoted furfural production from hemicellulose but with severe cellulose degradation. AlCl3 decreased cellulose degradation with considerable furfural yield and high glucan content in solid residues. The role of NaCl in furfural production and cellulose decomposition was also investigated in the single aqueous system using different acids as catalysts. Addition of NaCl significantly promoted furfural yield but also accelerated cellulose decomposition when FeCl3 or HC1 was used as catalyst. In the AlCl3-catalyzed system, NaCl had less influence on residue yield and its composition, although NaCl also promoted furfural production. The influence of MTHF on furfural yield, residue composition, and enzymatic hydrolysis of residue was also studied. Under the best conditions (0.45 g of bagasse, 9 mL of MTHF, 9 mL of water, 0.1 M AlCl3, 150 degrees C, 45 min, and 10 wt % NaCl), 58.6% furfural was obtained while more than 90% of cellulose remained in the residue. The organic phase was separated from the aqueous phase directly by decantation. After reuse of organic phase for 3 cycles, 11.5 g/L furfural was obtained. The catalyst-containing aqueous phase could be reused directly after decantation of the organic phase without loss of activity. The obtained residue was easy to hydrolyze and produced 89.3% glucose yield after 96-h enzymatic hydrolysis at low cellulase loading (30 FPU of cellulase/g glucan). |
| 学科主题 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 原文出处 | 10.1021/acssuschemeng.6b01847 |
| 语种 | 英语 |
| 公开日期 | 2017-06-06 |
| 源URL | [http://ir.xtbg.org.cn/handle/353005/10415]  |
| 专题 | 西双版纳热带植物园_生物能源研究组 |
| 推荐引用方式 GB/T 7714 | Li, Xing-kang,Fang, Zhen,Luo, Jia,et al. Coproduction of Furfural and Easily Hydrolyzable Residue from Sugar Cane Bagasse in the MTHF/Aqueous Biphasic System: Influence of Acid Species, NaCl Addition, and MTHF[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2016,4(10):5804-5813. |
| APA | Li, Xing-kang,Fang, Zhen,Luo, Jia,&Su, Tong-chao.(2016).Coproduction of Furfural and Easily Hydrolyzable Residue from Sugar Cane Bagasse in the MTHF/Aqueous Biphasic System: Influence of Acid Species, NaCl Addition, and MTHF.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,4(10),5804-5813. |
| MLA | Li, Xing-kang,et al."Coproduction of Furfural and Easily Hydrolyzable Residue from Sugar Cane Bagasse in the MTHF/Aqueous Biphasic System: Influence of Acid Species, NaCl Addition, and MTHF".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 4.10(2016):5804-5813. |
入库方式： OAI收割
来源：西双版纳热带植物园
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